Ethanol can be made either by fermentation or by the catalytic hydration of ethene. Table 4.1 compares some features of the two methods. Table 4.1 Feature F...

Assessment: Chemistry (9-1) 0971 | Paper 4 Mock 01 | Theory (Extended) Subject: Chemistry (9-1) - 0971

Question 1 Report

Ethanol can be made either by fermentation or by the catalytic hydration of ethene. Table 4.1 compares some features of the two methods.

Table 4.1
FeatureFermentationCatalytic hydration
Raw materialsugar (from plants)ethene
Temperatureabout 30 °Cabout 300 °C
Rate of reactionslowfast
Type of processbatchcontinuous
Purity of ethanolimpure / dilutepure

(a) State the raw material used to make ethanol in (i) fermentation and (ii) catalytic hydration. [2]
(b) State whether each of the two processes is a batch process or a continuous process. [2]
(c) Give one advantage that catalytic hydration has over fermentation. [1]
(d) Give one advantage that fermentation has over catalytic hydration. [1]
(e) Explain, in terms of resources, why fermentation is likely to become more important in the future. [2]
(f) State one everyday use of the ethanol produced by either method. [1]

Answer Details

This question tests a direct comparison of the two industrial routes to ethanol: fermentation and catalytic hydration of ethene.

(a) The raw materials are (i) sugar / glucose obtained from plants [1] and (ii) ethene, which comes from crude oil [1].

(b) Fermentation is a batch process (the vessel is filled, the reaction runs, then it is emptied and restarted) [1], whereas catalytic hydration is a continuous process (reactants flow in and product flows out without stopping) [1].

(c) An advantage of catalytic hydration (any one): it is faster, continuous, or gives a much purer product [1].

(d) An advantage of fermentation (any one): it uses a renewable raw material, needs a lower temperature, or uses less energy [1].

(e) In terms of resources, crude oil, the source of ethene, is finite and is running out [1]; whereas sugar / plant material is renewable and can be grown again each year [1]. As oil reserves fall, the renewable fermentation route becomes more important.

(f) One everyday use of ethanol (any one): as a fuel, as a solvent, or in alcoholic drinks [1].

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