CH\(_3\)C ≡ CCH(CH\(_3\))\(_2\) The IUPAC nomenclature of the compound above is

Assessment: JAMB UTME - Chemistry - 2025 Subject: Chemistry

Question 1 Report

CH\(_3\)C ≡ CCH(CH\(_3\))\(_2\)

The IUPAC nomenclature of the compound above is 

Answer Details

To name an organic compound using IUPAC nomenclature, follow these steps:

Step 1: Identify the structure. The compound is CH3C≡CCH(CH3)2. Writing it out carbon by carbon:

  • C-1: CH3
  • C-2: C (triple bond to C-3)
  • C-3: C (triple bond to C-2)
  • C-4: CH with two CH3 groups attached

Step 2: Find the longest carbon chain containing the triple bond. The four carbons above give a chain of 4. However, one of the methyl groups on C-4 can extend the chain to 5 carbons: C-1, C-2, C-3, C-4, C-5 (incorporating one methyl into the main chain). The remaining methyl group on C-4 becomes a branch.

Step 3: Number the chain to give the triple bond the lowest possible locants. Numbering from the CH3 end: the triple bond is at positions 2-3. This gives pent-2-yne.

Step 4: Name the substituent. The methyl branch is on C-4.

The complete IUPAC name is 4-methylpent-2-yne.

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