Calculate the pH of 0.001M KOH solution.

Assessment: JAMB UTME - Chemistry - 2025 Subject: Chemistry

Question 1 Report

Calculate the pH of 0.001M  KOH solution.

Answer Details

KOH is a strong base that dissociates completely in water:

\[\text{KOH} \rightarrow \text{K}^+ + \text{OH}^-\]

For a 0.001 M KOH solution, the concentration of hydroxide ions is:

\[[\text{OH}^-] = 0.001\;\text{M} = 10^{-3}\;\text{M}\]

First, calculate the pOH:

\[\text{pOH} = -\log[\text{OH}^-] = -\log(10^{-3}) = 3\]

Then, use the relationship between pH and pOH at 25 \(^\circ\)C:

\[\text{pH} + \text{pOH} = 14\]

\[\text{pH} = 14 - 3 = 11\]

The pH of 0.001 M KOH solution is 11.

Exam tip: For strong bases, first find [OH-] from the molarity, calculate pOH, then subtract from 14 to get pH. A pH of 11 confirms a basic solution, which is consistent with KOH being a strong alkali.

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