What is the cell notation for the cell reaction above?
Answer Details
The cell notation (also called line notation) for an electrochemical cell follows the convention:
Anode | Anode ion || Cathode ion | Cathode
where the single vertical line (|) represents a phase boundary, and the double vertical line (||) represents the salt bridge separating the two half-cells.
For the reaction Mg + Pb2+ → Mg2+ + Pb:
Anode (oxidation): Mg → Mg2+ + 2e-. Magnesium is oxidized, so it is the anode.
Cathode (reduction): Pb2+ + 2e- → Pb. Lead ions are reduced, so lead is the cathode.
Applying the convention:
Mg | Mg2+ || Pb2+ | Pb
Using the notation in the options (where I = | and II = ||), this is written as Mg|Mg2+||Pb2+|Pb.
The anode always appears on the left and the cathode on the right. Within each half-cell, the metal (solid phase) is written adjacent to the outer edge, and the ion (aqueous phase) is written adjacent to the salt bridge.