Cooking oil and water do not mix; they form two separate layers. The apparatus shown is used to separate a mixture of cooking oil and water. The oil forms t...

Assessment: Chemistry 0620 | Paper 4 Mock 01 | Theory (Extended) Subject: Chemistry - 0620

Question 1 Report

Cooking oil and water do not mix; they form two separate layers. The apparatus shown is used to separate a mixture of cooking oil and water. The oil forms the upper layer U and the water forms the lower layer L.

diagram

(a) Name the apparatus shown. [1]
(b) Describe how you would use this apparatus to obtain separate samples of the oil and the water. [3]
(c) Explain why the oil and water can be separated in this way. [2]

A student is given a mixture of the two solids in the table.

SolidSoluble in water?Soluble in ethanol?
copper(II) sulfateyesno
iodinenoyes

(d) Using the table, describe how the student could obtain a solution containing only iodine from a mixture of copper(II) sulfate and iodine, and name the technique used. [3]
(e) A different mixture contains salt (soluble in water) and sand (insoluble in water). Describe the steps needed to obtain pure dry salt and pure dry sand from this mixture. [4]
(f) Define the term solvent. [1]

Answer Details

This question tests separating immiscible liquids with a separating funnel, and choosing separation methods from solubility data.

(a) The apparatus is a separating funnel [1].

(b) To obtain separate samples:

  1. place the mixture in the funnel with the stopper in, and let the two layers settle so the oil (U) sits above the water (L) [1];
  2. open the tap and run the lower water layer L out into a beaker [1];
  3. close the tap the moment the oil-water boundary reaches it, then run the upper oil layer U into a separate container [1].

(c) The two liquids can be separated because they are immiscible (they do not mix and form separate layers) [1], and they have different densities, so the less dense oil floats on top of the more dense water [1].

(d) Using the solubility table, iodine dissolves in ethanol but copper(II) sulfate does not:

  1. add ethanol to the mixture so the iodine dissolves but the copper(II) sulfate stays solid [1];
  2. filter the mixture [1];
  3. the iodine solution passes through as the filtrate, giving a solution of only iodine (filtration) [1].

(e) To get pure dry salt and pure dry sand:

  1. add water and stir so the salt dissolves but the sand does not [1];
  2. filter to leave sand as the residue, then wash and dry the sand [1];
  3. evaporate the salt solution (filtrate) to remove most of the water [1];
  4. leave it to crystallise, then filter off and dry the salt crystals [1].

(f) A solvent is a liquid that dissolves a solute to form a solution [1].

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