Fig. 17.1 Fig. 17.1 is a representation of the structure of a typical metal such as magnesium. [FIGURE] (a) Name the type of structure and bonding present i...

Assessment: Chemistry 0620 | Paper 4 Mock 01 | Theory (Extended) Subject: Chemistry - 0620

Question 1 Report

0620-p4-atomic-structure-metallic-lattice-1

Fig. 17.1

Fig. 17.1 is a representation of the structure of a typical metal such as magnesium.

[FIGURE]

(a) Name the type of structure and bonding present in a metal. [2]
(b) Using ideas about the particles shown, describe the structure of a metal. Refer to positive ions and delocalised electrons in your answer. [3]
(c) Explain, in terms of this structure, why metals are good conductors of electricity. [2]
(d) Explain, in terms of this structure, why metals can be bent and hammered into shape (are malleable). [2]
(e) Metals are found on the left-hand side and centre of the Periodic Table. State, in terms of outer electrons, what atoms of metals have in common that leads to this type of bonding. [2]
(f) Magnesium is in Group II. Deduce the charge on a magnesium ion and hence the number of delocalised electrons each magnesium atom contributes to the structure. [2]
(g) Compare the electrical conductivity of solid magnesium with that of solid magnesium chloride, and explain the difference in terms of the particles that are free to move. [3]
(h) Explain why metals generally have high melting points. [2]

Answer Details

The figure for this question was not printed. The accepted model for the structure of a metal such as magnesium is a regular lattice of positive metal ions held together by a surrounding "sea" of delocalised electrons, shown below.

diagram

(a) The structure is a giant metallic structure (lattice) [1] and the bonding is metallic bonding [1].

(b) A metal consists of a regular, giant lattice of positive metal ions [1] surrounded by a "sea" of delocalised (mobile) electrons [1]; these electrons come from the outer shells of the atoms and are shared by, and free to move through, the whole structure [1].

(c) Because the delocalised electrons are free to move through the lattice [1], when a voltage is applied they drift and carry the electric current [1].

(d) When a force is applied the layers of positive ions slide over one another [1]; the electron sea moves with them so the metallic bonding is maintained, and the metal changes shape without shattering, which is why it is malleable [1].

(e) Metal atoms have a small number of outer-shell electrons [1] which they lose (release) easily to become the delocalised electron sea [1].

(f) Magnesium is in Group II, so each atom loses 2 electrons to give a 2+ ion, \(\text{Mg}^{2+}\) [1]; each atom therefore contributes 2 delocalised electrons [1] to the structure.

(g) Solid magnesium conducts electricity [1], but solid magnesium chloride does not [1]: in the metal the delocalised electrons are free to move, whereas in solid \(\text{MgCl}_2\) the ions are locked in fixed positions in the lattice and cannot move to carry charge [1].

(h) There is strong electrostatic attraction between the positive ions and the sea of delocalised electrons [1], and a large amount of energy is needed to overcome this attraction (break the metallic bonds), so metals generally have high melting points [1].

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