JAMB UTME - Chemistry - 2022
Question 1 Report
Which of the following conducts electricity
Answer Details
Graphite is the option that conducts electricity.
Question 2 Report
2-methylprop-1-ene is a structural isomer of?
Question 3 Report
The following non-metal form acidic oxides with oxygen except?
Answer Details
An acidic oxide is an oxide that reacts with water to form an acidic solution. Non-metals have a greater tendency to form acidic oxides than metals. Therefore, among the given options, the non-metal that does not form an acidic oxide with oxygen would be the one that does not react with water to form an acidic solution. Out of the given options, chlorine is the non-metal that does not form acidic oxides with oxygen. Chlorine reacts with oxygen to form a number of oxides such as chlorine monoxide (Cl2O), chlorine dioxide (ClO2), and chlorine trioxide (ClO3), but none of these oxides react with water to form an acidic solution. Instead, they react with water to form oxyacids or oxoacids such as hypochlorous acid (HClO), chlorous acid (HClO2), and chloric acid (HClO3), which are stronger acids than the oxides. Therefore, the correct answer is chlorine.
Question 4 Report
An organic compound decolourized acidified KMnO4 solution but failed to react with ammonical AgNO3 solution. The organic compound is likely?
Answer Details
The given information suggests that the organic compound is an unsaturated compound (because it decolorized the acidified KMnO4 solution), but it does not contain a functional group that reacts with ammonical AgNO3 solution. Therefore, the likely organic compound is an alkene or an alkyne. Carboxylic acids can also react with acidified KMnO4 solution, but they would also react with ammonical AgNO3 solution to form a silver carboxylate salt. Alkanes are saturated compounds and do not react with either reagent, so they would not decolorize the acidified KMnO4 solution. Therefore, based on the given information, the most likely option is either an alkene or an alkyne.
Question 5 Report
A piece of radioactive element has initially 8.0×10^22 atoms. The half life of two days after 16 days the number of atom is
Question 6 Report
A chemical widely used as a fertilizer is?
Answer Details
The chemical widely used as a fertilizer is nitrochalk. Nitrochalk is a type of fertilizer that contains a mixture of ammonium nitrate and calcium carbonate. Ammonium nitrate provides the necessary nitrogen for plant growth, while calcium carbonate helps to balance the soil's pH level. This combination of nutrients helps to promote healthy plant growth and increase crop yields. Nitrochalk is commonly used in agriculture and gardening to fertilize crops such as corn, wheat, and soybeans, as well as fruits and vegetables.
Question 7 Report
Which of the following constitutes a mixture? I. Petroleum II. Rubber latex III. Vulcanizer’s solution IV. Carbon (iv) sulphide
Answer Details
Question 8 Report
The removal of rust from iron by treatment with tetraoxosulphate (vi) acid is based on the
Answer Details
Question 9 Report
Copper (II) tetraoxosulphate (IV) is widely used as
Answer Details
Copper (II) tetraoxosulphate (IV), also known as copper sulfate or CuSO4, is widely used as a fungicide and a disinfectant. As a fungicide, copper sulfate is effective in controlling fungal diseases in plants, including mildew, leaf spots, and blights. It is also used as a fungicide in swimming pools to prevent the growth of algae. As a disinfectant, copper sulfate is effective in killing bacteria and viruses. It is used in a variety of applications, including in the production of animal feed, as a preservative for wood, and in water treatment to kill bacteria and algae. While copper sulfate has been used as a fertilizer in the past, its use in this capacity has largely been replaced by other compounds. It is not commonly used as a purifier.
Question 10 Report
An organic compound which liberate carbon(iv)oxide from trioxocarbonate(iv) solution is likely to be?
Answer Details
The organic compound that liberates carbon(iv)oxide from trioxocarbonate(iv) solution is CH3COOH (acetic acid). When acetic acid is added to a solution of trioxocarbonate(iv) (carbonate) it reacts to form carbon(iv)oxide gas, water and a salt. The balanced chemical equation for the reaction is: 2CH3COOH + Na2CO3 → CO2 + 2H2O + 2NaCH3COO The carbon(iv)oxide gas is released as bubbles, causing the solution to fizz. Therefore, CH3COOH is the organic compound that liberates carbon(iv)oxide from trioxocarbonate(iv) solution.
Question 11 Report
There is a large temperature interval between the melting point and the boiling point of metal because:
Answer Details
The correct answer is: "melting does not break the metallic bond but boiling does." The metallic bond is the force of attraction between metal atoms, which holds them together to form a solid. When a metal is heated, its temperature increases, and at a certain point, the energy provided by the heat is enough to overcome the metallic bond and cause the metal to melt. However, even in the liquid state, the metallic bond remains intact, which is why metals have a very high melting point. On the other hand, when the temperature is further increased, the energy provided by the heat becomes enough to break the metallic bond, and the metal atoms become completely detached from one another. This results in the metal boiling and turning into a gas. Because the metallic bond is much stronger than other types of intermolecular forces, such as van der Waals forces, it requires a lot of energy to break, resulting in a large temperature interval between the melting point and boiling point of metal.
Question 12 Report
The reactions below represent neutralization reaction, in which of them is the value of ΔH highest?
Answer Details
The reaction with the highest ΔH (change in enthalpy) would be the reaction between HCL and NaOH, which forms NaCL and H2O. This is because the formation of water releases energy in the form of heat, which is reflected in the positive ΔH value for this reaction. When an acid and a base react, they neutralize each other and form a salt and water, with the release of heat being a sign of an exothermic reaction.
Question 13 Report
Electrons enter into orbitals in order of increasing energy as exemplified by?
Answer Details
Question 14 Report
Which of the following is stable to heat
Answer Details
Out of the given options, K2CO3 is stable to heat.
Question 15 Report
| GAS | \( \mathrm{CO_2} \) | \( \mathrm{N_2} \) | \( \mathrm{O_2} \) |
| % BY VOLUME | 4 | 72 | 24 |
The above table shows the compositions of the atmosphere of planet X. Which of these gases are present in higher percentages on earth?
Answer Details
Question 16 Report
The IUPAC name for CICH2-CH2-CH2-OH is
Answer Details
The IUPAC name for CICH2-CH2-CH2-OH is 3-chloropropan-1-ol. To name the compound using the IUPAC nomenclature system, we start by identifying the longest continuous chain of carbon atoms that contains the functional group (-OH). In this case, the longest chain contains three carbon atoms, so the root name is propane. Next, we identify the position of the substituent (-Cl) on the chain. The substituent is attached to the third carbon atom in the chain, so the name of the compound becomes 3-chloropropane. Finally, we add the suffix -ol to indicate that the compound contains an alcohol functional group (-OH), so the complete name of the compound is 3-chloropropan-1-ol. Therefore, the correct answer is 3-chloropropan-1-ol.
Question 17 Report
\(\mathrm{N_2O_4}\) ? \(2\mathrm{NO_2}\) (? = -ve)
From the reaction above, which of these conditions would produce the highest equilibrium yield for \(\mathrm{N_2O_4}\)?
Answer Details
The highest equilibrium yield of N2O4 would be produced at low temperature and low pressure. In a chemical reaction, the position of the equilibrium can be influenced by changing the temperature or pressure. A decrease in temperature or an increase in pressure favors the side of the reaction with the fewer moles of gas (in this case, N2O4). This means that, if the temperature is low and the pressure is low, there will be more N2O4 at equilibrium, as the reaction will shift to the right to counteract the reduction in the concentration of N2O4. So, low temperature and low pressure would produce the highest equilibrium yield of N2O4.
Question 18 Report
The IUPAC nomenclature of the structure is
Answer Details
The IUPAC nomenclature of the structure is "2-chloro-2-methylbutane". The name is derived by first identifying the longest carbon chain, which in this case contains four carbon atoms (butane). The carbon chain is numbered from one end to the other, giving the substituents the lowest possible numbers. Starting from either end, we can see that the first carbon atom has a chlorine atom attached to it, which is represented by the prefix "chloro-". Moving along the chain, the second carbon atom has a methyl group attached to it, which is represented by the prefix "methyl-". Since the substituents are in the second position from each other, we use the prefix "di-" to indicate two substituents in this position. Finally, we use the suffix "-ane" to indicate that the molecule is an alkane. Therefore, the correct name for this molecule is "2-chloro-2-methylbutane".
Question 19 Report
The dehydration of \( \mathrm{CH_3CH_2CH_2CH_2OH} \) will give?
Question 20 Report
Which of the following substances is not a homogeneous mixture?
Answer Details
The substance that is not a homogeneous mixture is flood water. Flood water is typically a mixture of various substances, such as sediment, dirt, debris, and organic matter, that have been carried along by the water. As such, flood water is usually a heterogeneous mixture, meaning that it does not have a uniform composition throughout. In contrast, filtered sea water, soft drinks, and writing ink are all examples of homogeneous mixtures, where the components are evenly distributed and the mixture has a uniform composition throughout.
Question 21 Report
Which of the following statement is TRUE of the complete hydrolysis of a glyceride by sodium hydroxide?
Answer Details
The statement that is TRUE of the complete hydrolysis of a glyceride by sodium hydroxide is: - 3 moles of NaOH are required for each mole of glyceride. During the hydrolysis of a glyceride (a triglyceride), the ester bonds between the fatty acid chains and glycerol are broken by the action of a strong base like sodium hydroxide. This results in the formation of glycerol and the corresponding salts of fatty acids, which are commonly known as "soaps." The reaction can be represented by the following equation: Triglyceride + 3 NaOH → 3 soap + glycerol As per the equation, 3 moles of NaOH are required to hydrolyze one mole of glyceride, and 3 moles of soap and one mole of glycerol are produced. The use of concentrated sulfuric acid (H2SO4) is not essential for the completion of the reaction, but it can be used as a catalyst to speed up the reaction.
Question 22 Report
Answer Details
The addition of charcoal to the filter bed of sand during water treatment for township supply is to remove odors and improve the taste of the water. Charcoal is a porous material that can adsorb impurities and chemicals from the water, such as dissolved organic matter that can contribute to unpleasant tastes and odors. This process helps to produce a better-quality drinking water that is free from unpleasant tastes and odors. It should be noted that while the addition of charcoal can help remove impurities, it does not kill germs or prevent tooth decay or goiter. Other water treatment methods, such as disinfection with chlorine or ultraviolet light, are required to kill harmful microorganisms and ensure the safety of the drinking water.
Question 23 Report
6g of Mg was to 100cm3 of 1 moldm3 H2 SO4 . What mass of Mg remained undissolved? (Mg = 24)
Answer Details
The balanced chemical equation for the reaction between magnesium (Mg) and sulfuric acid (H2SO4) is: Mg + H2SO4 -> MgSO4 + H2 According to the equation, one mole of Mg reacts with one mole of H2SO4 to produce one mole of magnesium sulfate (MgSO4) and one mole of hydrogen gas (H2). Since the concentration of the sulfuric acid is 1 moldm3, this means that there is one mole of H2SO4 in every 1 liter (1000 cm3) of solution. To determine the amount of Mg that reacts with the H2SO4, we need to use stoichiometry. One mole of Mg reacts with one mole of H2SO4, so the amount of Mg that reacts with 1 moldm3 of H2SO4 is given by: 6g / 24g/mol = 0.25 mol Since the reaction is 1:1, this means that 0.25 mol of H2SO4 is consumed in the reaction. The volume of the solution is 100cm3 (0.1 dm3), so the amount of H2SO4 in the solution is: 1 mol/dm3 x 0.1 dm3 = 0.1 mol The amount of H2SO4 that remains after the reaction is: 0.1 mol - 0.25 mol = -0.15 mol This negative value means that all of the H2SO4 was consumed in the reaction, and there is excess Mg left over. The mass of Mg that remains undissolved is given by: 0.15 mol x 24g/mol = 3.6g Therefore, the correct answer is 3.6g.
Question 24 Report
which of these compounds exhibits resonance
Answer Details
The compound that exhibits resonance is benzene.
Question 25 Report
On the basis of the electrochemical series, which of these ions will show the greater tendency to be discharged at the cathode in an electrolytic cell
Answer Details
The electrochemical series is a list of metals and ions arranged in order of their decreasing tendency to lose or gain electrons, and thus, their ability to act as reducing or oxidizing agents. The higher the position of a metal or ion in the electrochemical series, the greater its tendency to lose electrons and undergo oxidation, while the lower its position, the greater its tendency to gain electrons and undergo reduction. In an electrolytic cell, the cathode is the electrode where reduction occurs, meaning that cations (positively charged ions) are attracted and gain electrons to form neutral atoms or molecules. Based on the electrochemical series, the ion with the higher position in the series will have a greater tendency to gain electrons and be discharged at the cathode, while the ion with the lower position will have a lower tendency and may not be discharged at all. Among the given options, the electrochemical series order is: Cu2+ > Sn2+ > Fe2+ > Zn2+ Therefore, Cu2+ has the highest tendency to be discharged at the cathode and undergo reduction, while Zn2+ has the lowest tendency. So, in an electrolytic cell, Cu2+ will be discharged at the cathode, while Zn2+ may not be discharged at all, depending on the conditions of the cell.
Question 26 Report
The sulphide that is commonly used in coating electric fluorescent tubes is?
Answer Details
The sulphide commonly used in coating electric fluorescent tubes is Zinc Sulphide. Zinc Sulphide is a type of material that glows when it is exposed to ultraviolet light. When ultraviolet light is generated inside a fluorescent tube, it excites the Zinc Sulphide particles, causing them to emit visible light. This visible light is what we see as the bright light coming from the tube. So, Zinc Sulphide acts as a phosphor and helps in producing the bright light in fluorescent tubes.
Question 27 Report
What volume of (dm\(^{3}\)) of water will be added to 10dm\(^{3}\) of 2.0 mol/dm\(^{3}\) HCL acid solution to give a final solution of 0.5 mol/dm\(^{3}\)?
Answer Details
Question 28 Report
Crude petroleum is converted to useful products by the process of?
Answer Details
The process of converting crude petroleum into useful products is known as fractional distillation. Crude petroleum is a mixture of different hydrocarbons, and fractional distillation separates these hydrocarbons based on their boiling points. During the process of fractional distillation, crude petroleum is heated to a high temperature, and the resulting vapors are passed through a tower called a fractionating column. This column contains a series of trays, and each tray contains a specific temperature range. As the vapors rise up the column, they cool and condense into liquids on the tray with a temperature that matches their boiling point. The liquids are then collected and further refined into useful products like gasoline, diesel, jet fuel, and heating oil. Fractional distillation is an important process because it allows us to separate and purify the different components of crude petroleum, which have different properties and uses. For example, gasoline has a lower boiling point and is more volatile than diesel fuel, which makes it ideal for use in cars. By separating these components, we can create products that meet specific needs and requirements.
Question 29 Report
Complete dehydrogenation of ethyne yields
Question 30 Report
The function of sulphur during the vulcanization of rubber is to
Answer Details
The function of sulphur during the vulcanization of rubber is to form chains which bind rubber molecules together.
Question 31 Report
When heat is absorbed during a chemical reaction, the reaction is said to be
Answer Details
When heat is absorbed during a chemical reaction, the reaction is said to be endothermic. Endothermic reactions are characterized by the absorption of heat energy from the surroundings. In other words, the reactants absorb energy from the environment, usually in the form of heat, to form the products. As a result, the temperature of the surroundings decreases, and the reaction feels cold to the touch. Endothermic reactions can be found in many natural processes, such as photosynthesis, melting of ice, and the evaporation of liquids. These processes require energy to occur, and they absorb heat from the surroundings to power the reaction.
Question 33 Report
A quantity of air passed through a weighted amount of alkaline pyrogallol. An increase in the weight of the pyrogallol would result from the absorption of
Answer Details
When air is passed through alkaline pyrogallol, the oxygen in the air is absorbed by the pyrogallol, resulting in an increase in the weight of the pyrogallol. The other gases in air, namely nitrogen, neon, and argon, do not react with pyrogallol under these conditions. Therefore, the answer is oxygen.
Question 35 Report
Which of the following increases as boiling water changes to steam?
Answer Details
The degree of disorder of the system increases as boiling water changes to steam. When water is boiled and changes to steam, the water molecules gain energy and become more disordered, which means that the molecules move more rapidly and the entropy of the system increases. The temperature of the system also increases during this process, but the degree of disorder is the factor that specifically increases as the water changes to steam. The number of molecules and activation energy remain constant during this phase transition.
Question 36 Report
Which of the following roles does sodium chloride play in preparation? It
Answer Details
The role that sodium chloride (NaCl) plays in soap preparation is to separate soap from glycerol. When fats or oils are hydrolyzed with an alkali, such as sodium hydroxide (NaOH), the result is a mixture of soap and glycerol. Adding NaCl to this mixture helps to induce the precipitation of the soap, allowing it to be separated from the glycerol. This process is known as "salting out" and is used to purify the soap and remove impurities. Sodium chloride does not react with glycerol or accelerate the decomposition of fat and oil. Also, it does not convert the fatty acid to its sodium salt as this conversion is done by the alkali (such as NaOH) during the saponification process.
Question 37 Report
Wrought iron is obtained by heating cast iron in a furnace with?
Answer Details
Wrought iron is a type of iron that is very malleable and ductile, meaning it can be easily shaped and formed into various objects. It is obtained by heating cast iron in a furnace with haematite, also known as iron(III) oxide. When cast iron is heated with haematite in a furnace, a chemical reaction takes place where the haematite reacts with the carbon in the cast iron to produce carbon dioxide gas. This reaction also produces molten iron, which is then further heated to remove any impurities like sulfur and phosphorus. This molten iron is then poured into molds to form ingots of wrought iron. Therefore, haematite is essential in the process of obtaining wrought iron from cast iron.
Question 38 Report
The oxidation number of oxygen in BaO2 is
Answer Details
To determine the oxidation number of oxygen in BaO2, we can use the fact that the overall charge of a compound must be zero. Barium (Ba) is a Group 2 element and has an oxidation state of +2. The compound BaO2 has no net charge, so the sum of the oxidation states of all the atoms must be zero. Let x be the oxidation state of oxygen in BaO2. Therefore, we have: (+2) + 2(x) = 0 Solving for x, we get: x = -1 Therefore, the oxidation number of oxygen in BaO2 is -1.
Question 39 Report
When marble is heated to 1473K, another whiter solid is obtained which reacts vigoriously with water to give an alkaline solution. The solution contains
Answer Details
The white solid obtained when marble (calcium carbonate, CaCO3) is heated to 1473K is calcium oxide (CaO), also known as quicklime. When quicklime reacts vigorously with water, it forms calcium hydroxide (Ca(OH)2), which is an alkaline solution. Therefore, the solution obtained from the reaction of quicklime with water contains calcium hydroxide (Ca(OH)2).
Question 40 Report
Mixing aqueos solution of barium hydroxide and sodium tetraoxocarbonate (iv) yields a white precipitate of
Answer Details
Mixing aqueous solutions of barium hydroxide and sodium tetraoxocarbonate (IV) would result in a chemical reaction that produces a white precipitate of barium tetraoxocarbonate (IV). The balanced chemical equation for this reaction is: Ba(OH)2(aq) + Na2CO3(aq) → BaCO3(s) + 2NaOH(aq) In the above equation, the barium hydroxide (Ba(OH)2) reacts with sodium tetraoxocarbonate (IV) (Na2CO3) to form barium tetraoxocarbonate (IV) (BaCO3), which is a white precipitate, and sodium hydroxide (NaOH). Therefore, the correct option is 4) Barium tetraoxocarbonate.
