Question 1 Report
(a)Define the term solubility.
(b) The table below gives the solubility of salt Z at various mperatures
| Temperature (°C) | 0 | 10 | 20 | 30 | 40 | 50 | 60 |
| Solubility (mol dm\(^{-3}\)) | 0.13 | 0.21 | 0.31 | 0.45 | 0.63 | 0.85 | 1.10 |
(i) Plot a graph of solubility against temperature.
(ii) From the graph determine the solubility of salt Z at 35°C.
(iii) If 100cm\(^{-3}\) of the saturated solution is cooled from 55°C to 35°C, calculate the mass of salt Z that would crystallize out. [Molar mass of salt Z = 100 g]
(c)(i) Write a balanced equation to illustrate the reaction of AI\(_2\)O\(_3\) with dilute I. HCI; II. NaOH.
(ii) What is the name given to an oxide that exhibits both acidic and basic properties?
(iii) Give one metallic oxide which exhibite these properties.
(d)(i) Determine the oxidation number of: I. Al in [Al (H\(_2\)O)\(_6\)]\(^{3+}\); II. H in NaH.
(ii) Give the IUPAC name of each of the following substances; I. CuSO\(_4\).5H\(_2\)O; II. CaCO\(_3\); Ill. KMnO\(_4\).
(a) Solubility is the maximum amount of a solute that dissolves in 1 dm3 of solution at a specified temperature to form a saturated solution.
(b)(i) The solubility curve of salt Z is plotted below. Temperature is on the horizontal axis and solubility is on the vertical axis.
(ii) From the graph, at 35°C:
Solubility of Z = 0.54 mol dm−3.
(iii) From the graph:
Decrease in solubility:
\[0.97-0.54=0.43\ \text{mol dm}^{-3}\]
Volume of saturated solution = \(100\text{ cm}^3=0.100\text{ dm}^3\).
Moles of salt crystallized:
\[0.43\times0.100=0.043\ \text{mol}\]
\[\text{Mass crystallized}=0.043\times100=\boxed{4.3\ \text{g}}\]
(c)(i)
I. Reaction with dilute hydrochloric acid:
\[\mathrm{Al_2O_3(s)+6HCl(aq)\rightarrow2AlCl_3(aq)+3H_2O(l)}\]
II. Reaction with sodium hydroxide solution:
\[\mathrm{Al_2O_3(s)+2NaOH(aq)+3H_2O(l)\rightarrow2NaAl(OH)_4(aq)}\]
(c)(ii) Such an oxide is called an amphoteric oxide.
(c)(iii) Zinc oxide, \(\mathrm{ZnO}\), is an amphoteric metallic oxide.
(d)(i)
I. In \(\mathrm{[Al(H_2O)_6]^{3+}}\), water is neutral. Therefore, oxidation number of Al = +3.
II. In \(\mathrm{NaH}\), Na is \(+1\). Therefore, oxidation number of H = −1.
(d)(ii)
| Formula | IUPAC name |
|---|---|
| \(\mathrm{CuSO_4\cdot5H_2O}\) | Copper(II) tetraoxosulfate(VI) pentahydrate |
| \(\mathrm{CaCO_3}\) | Calcium trioxocarbonate(IV) |
| \(\mathrm{KMnO_4}\) | Potassium tetraoxomanganate(VII) |
Everything you need to excel in your exams