TEST OF PRACTICAL KNOWLEDGE QUESTION Credit will be given for strict adherence to the instructions, for observations precisely recorded, and for accurate in...
Credit will be given for strict adherence to the instructions, for observations precisely recorded, and for accurate inferences. All tests, observations, and inferences must be clearly entered in your answer book, in ink, at the time they are made.
C and D are two aqueous solutions. Carry out the following exercises on C and D. Record your observations and identify any gas(es) evolved. State the conclusion you draw from the result of each test.
(a)(i) To about \(2\ \mathrm{cm}^3\) portion of C, add \(\mathrm{NaOH}_{(aq)}\) In drops until in excess. Warm the mixture
(ii) To another \(2\ \mathrm{cm}^3\) portion of C, add \(\mathrm{HCl}_{(aq)}\) followed by \(\mathrm{BaCl}_{2(aq)}\)
(b)(i) (ii) To another \(2\ \mathrm{cm}^3\) portion of D, add add \(\mathrm{NH}_{3(aq)}\) drops and then in excess.
(ii) To about \(2\ \mathrm{cm}^3\) portion of D, add \(\mathrm{AgNO}_{3(aq)}\) followed by \(\mathrm{HNO}_{3(aq)}\)
TESTS ON SOLUTIONS C AND D
Test
Observation
Inference
(a)(i) To C, add NaOH(aq) dropwise and then in excess. Warm.
No visible reaction or precipitate is formed. On warming, a colourless gas with a pungent, choking smell is evolved. The gas turns damp red litmus paper blue and forms white fumes with hydrogen chloride gas.
The gas is ammonia, NH3. Ammonium ion, NH4+, is present.
(a)(ii) To a fresh portion of C, add HCl(aq), followed by BaCl2(aq).
No visible reaction occurs on adding dilute hydrochloric acid. A white precipitate forms on adding barium chloride solution.
Tetraoxosulphate(VI) ion, SO42−, is present.
(b)(i) To D, add NH3(aq) dropwise and then in excess.
A reddish-brown precipitate is formed. The precipitate is insoluble in excess aqueous ammonia.
Iron(III) ion, Fe3+, is present.
(b)(ii) To a fresh portion of D, add AgNO3(aq), followed by HNO3(aq).
A white precipitate is formed with silver nitrate solution. The precipitate remains insoluble on adding dilute nitric acid.
Chloride ion, Cl−, is present.
Conclusion: C contains NH4+ and SO42− ions and is ammonium tetraoxosulphate(VI),
0(NH4)2SO4. D contains Fe3+ and Cl− ions and is iron(III) chloride, FeCl3.
(a)(i) To C, add NaOH(aq) dropwise and then in excess. Warm.
No visible reaction or precipitate is formed. On warming, a colourless gas with a pungent, choking smell is evolved. The gas turns damp red litmus paper blue and forms white fumes with hydrogen chloride gas.
The gas is ammonia, NH3. Ammonium ion, NH4+, is present.
(a)(ii) To a fresh portion of C, add HCl(aq), followed by BaCl2(aq).
No visible reaction occurs on adding dilute hydrochloric acid. A white precipitate forms on adding barium chloride solution.
Tetraoxosulphate(VI) ion, SO42−, is present.
(b)(i) To D, add NH3(aq) dropwise and then in excess.
A reddish-brown precipitate is formed. The precipitate is insoluble in excess aqueous ammonia.
Iron(III) ion, Fe3+, is present.
(b)(ii) To a fresh portion of D, add AgNO3(aq), followed by HNO3(aq).
A white precipitate is formed with silver nitrate solution. The precipitate remains insoluble on adding dilute nitric acid.
Chloride ion, Cl−, is present.
Conclusion: C contains NH4+ and SO42− ions and is ammonium tetraoxosulphate(VI),
0(NH4)2SO4. D contains Fe3+ and Cl− ions and is iron(III) chloride, FeCl3.