(a) Write an equation for the reaction of chlorine with (i) potassium iodide solution; (ii) zinc on heating (b) Identify the product Q in the following reac...

Assessment: WAEC SSCE - Chemistry - 1998 (Essay) Subject: Chemistry

Question 1 Report

(a) Write an equation for the reaction of chlorine with

(i) potassium iodide solution;

(ii) zinc on heating

(b) Identify the product Q in the following reaction: Cl\(_2\) + 2NaOH \(\to\) NaCl + H\(_2\)O + Q.

Answer Details

(a) Reactions of chlorine:

  • (i) With potassium iodide solution (chlorine displaces iodine): \[Cl_2 + 2KI \rightarrow 2KCl + I_2\]
  • (ii) With zinc on heating: \[Zn + Cl_2 \rightarrow ZnCl_2\]

(b) In \(Cl_2 + 2NaOH \rightarrow NaCl + H_2O + Q\) (cold, dilute sodium hydroxide), the product Q is sodium chlorate(I) (sodium oxochlorate(I) / sodium hypochlorite), \(NaOCl\).

The balanced equation is: \[Cl_2 + 2NaOH \rightarrow NaCl + NaOCl + H_2O\]

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