JAMB UTME - Chemistry - 2022

N2 ${}_2$O4 ${}_4$ ? 2NO2 ${}_2$          (? = -ve)

From the reaction above, which of these conditions would produce the highest equilibrium yield for N2 ${}_2$O4 ${}_4$?

Détails de la réponse

The highest equilibrium yield of N2O4 would be produced at low temperature and low pressure. In a chemical reaction, the position of the equilibrium can be influenced by changing the temperature or pressure. A decrease in temperature or an increase in pressure favors the side of the reaction with the fewer moles of gas (in this case, N2O4). This means that, if the temperature is low and the pressure is low, there will be more N2O4 at equilibrium, as the reaction will shift to the right to counteract the reduction in the concentration of N2O4. So, low temperature and low pressure would produce the highest equilibrium yield of N2O4.

Hard water is water with high concentrations of dissolved ions, in particular calcium and

Détails de la réponse

Hard water is water that contains high amounts of dissolved minerals, specifically calcium and magnesium ions. These minerals come from the rocks and soil that the water flows through and can accumulate in the water as it travels to your home. When you use hard water, it can leave mineral deposits on your pipes, fixtures, and appliances, which can reduce their efficiency and lifespan. It can also make soap less effective and leave your skin feeling dry and itchy. Therefore, it is important to treat hard water if it is a problem in your area.

A quantity of air passed through a weighted amount of alkaline pyrogallol. An increase in the weight of the pyrogallol would result from the absorption of

Détails de la réponse

When air is passed through alkaline pyrogallol, the oxygen in the air is absorbed by the pyrogallol, resulting in an increase in the weight of the pyrogallol. The other gases in air, namely nitrogen, neon, and argon, do not react with pyrogallol under these conditions. Therefore, the answer is oxygen.

Which of the following increases as boiling water changes to steam?

Détails de la réponse

The degree of disorder of the system increases as boiling water changes to steam. When water is boiled and changes to steam, the water molecules gain energy and become more disordered, which means that the molecules move more rapidly and the entropy of the system increases. The temperature of the system also increases during this process, but the degree of disorder is the factor that specifically increases as the water changes to steam. The number of molecules and activation energy remain constant during this phase transition.

An organic compound which liberate carbon(iv)oxide from trioxocarbonate(iv) solution is likely to be?

Détails de la réponse

The organic compound that liberates carbon(iv)oxide from trioxocarbonate(iv) solution is CH3COOH (acetic acid). When acetic acid is added to a solution of trioxocarbonate(iv) (carbonate) it reacts to form carbon(iv)oxide gas, water and a salt. The balanced chemical equation for the reaction is: 2CH3COOH + Na2CO3 → CO2 + 2H2O + 2NaCH3COO The carbon(iv)oxide gas is released as bubbles, causing the solution to fizz. Therefore, CH3COOH is the organic compound that liberates carbon(iv)oxide from trioxocarbonate(iv) solution.

A metal which can be used as sacrificial anode for preventing corrosion of length of iron pipe is

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Chlorine is a common bleaching agent. This is not true with

Détails de la réponse

Chlorine is not a common bleaching agent for wet litmus paper, wet pawpaw leaf, and most wet fabric dyes. It is commonly used as a bleaching agent for printer's ink.

Crude petroleum is converted to useful products by the process of?

Détails de la réponse

The process of converting crude petroleum into useful products is known as fractional distillation. Crude petroleum is a mixture of different hydrocarbons, and fractional distillation separates these hydrocarbons based on their boiling points. During the process of fractional distillation, crude petroleum is heated to a high temperature, and the resulting vapors are passed through a tower called a fractionating column. This column contains a series of trays, and each tray contains a specific temperature range. As the vapors rise up the column, they cool and condense into liquids on the tray with a temperature that matches their boiling point. The liquids are then collected and further refined into useful products like gasoline, diesel, jet fuel, and heating oil. Fractional distillation is an important process because it allows us to separate and purify the different components of crude petroleum, which have different properties and uses. For example, gasoline has a lower boiling point and is more volatile than diesel fuel, which makes it ideal for use in cars. By separating these components, we can create products that meet specific needs and requirements.

Mixing aqueos solution of barium hydroxide and sodium tetraoxocarbonate (iv) yields a white precipitate of

Détails de la réponse

Mixing aqueous solutions of barium hydroxide and sodium tetraoxocarbonate (IV) would result in a chemical reaction that produces a white precipitate of barium tetraoxocarbonate (IV). The balanced chemical equation for this reaction is: Ba(OH)2(aq) + Na2CO3(aq) → BaCO3(s) + 2NaOH(aq) In the above equation, the barium hydroxide (Ba(OH)2) reacts with sodium tetraoxocarbonate (IV) (Na2CO3) to form barium tetraoxocarbonate (IV) (BaCO3), which is a white precipitate, and sodium hydroxide (NaOH). Therefore, the correct option is 4) Barium tetraoxocarbonate.

A sample of gas exerts a pressure of 8.2 atm when confined in a 2.93 dm3 container at 20c. The number of moles of gas in the sample is

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When heat is absorbed during a chemical reaction, the reaction is said to be

Détails de la réponse

When heat is absorbed during a chemical reaction, the reaction is said to be endothermic. Endothermic reactions are characterized by the absorption of heat energy from the surroundings. In other words, the reactants absorb energy from the environment, usually in the form of heat, to form the products. As a result, the temperature of the surroundings decreases, and the reaction feels cold to the touch. Endothermic reactions can be found in many natural processes, such as photosynthesis, melting of ice, and the evaporation of liquids. These processes require energy to occur, and they absorb heat from the surroundings to power the reaction.

The IUPAC nomenclature of the structure is

Détails de la réponse

The IUPAC nomenclature of the structure is "2-chloro-2-methylbutane". The name is derived by first identifying the longest carbon chain, which in this case contains four carbon atoms (butane). The carbon chain is numbered from one end to the other, giving the substituents the lowest possible numbers. Starting from either end, we can see that the first carbon atom has a chlorine atom attached to it, which is represented by the prefix "chloro-". Moving along the chain, the second carbon atom has a methyl group attached to it, which is represented by the prefix "methyl-". Since the substituents are in the second position from each other, we use the prefix "di-" to indicate two substituents in this position. Finally, we use the suffix "-ane" to indicate that the molecule is an alkane. Therefore, the correct name for this molecule is "2-chloro-2-methylbutane".

The pollutant usually presents in a city which generates its electricity from coal?

Détails de la réponse

The pollutant that is usually present in a city that generates its electricity from coal is sulfur dioxide (SO2), also known as sulfur(iv)oxide. When coal is burned to generate electricity, sulfur compounds in the coal are released into the air as SO2. This gas can react with other pollutants and atmospheric conditions to form smog, which can be harmful to human health and the environment. Therefore, it is important to reduce the use of coal in electricity generation and promote cleaner and more sustainable energy sources to reduce the levels of SO2 and other harmful pollutants in the air.

Silver chloride turns gray when exposed to sunlight because

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A chemical widely used as a fertilizer is?

Détails de la réponse

The chemical widely used as a fertilizer is nitrochalk. Nitrochalk is a type of fertilizer that contains a mixture of ammonium nitrate and calcium carbonate. Ammonium nitrate provides the necessary nitrogen for plant growth, while calcium carbonate helps to balance the soil's pH level. This combination of nutrients helps to promote healthy plant growth and increase crop yields. Nitrochalk is commonly used in agriculture and gardening to fertilize crops such as corn, wheat, and soybeans, as well as fruits and vegetables.

Alkanes are used mainly?

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The following non-metal form acidic oxides with oxygen except?

Détails de la réponse

An acidic oxide is an oxide that reacts with water to form an acidic solution. Non-metals have a greater tendency to form acidic oxides than metals. Therefore, among the given options, the non-metal that does not form an acidic oxide with oxygen would be the one that does not react with water to form an acidic solution. Out of the given options, chlorine is the non-metal that does not form acidic oxides with oxygen. Chlorine reacts with oxygen to form a number of oxides such as chlorine monoxide (Cl2O), chlorine dioxide (ClO2), and chlorine trioxide (ClO3), but none of these oxides react with water to form an acidic solution. Instead, they react with water to form oxyacids or oxoacids such as hypochlorous acid (HClO), chlorous acid (HClO2), and chloric acid (HClO3), which are stronger acids than the oxides. Therefore, the correct answer is chlorine.

The reactions below represent neutralization reaction, in which of them is the value of ΔH highest?

Détails de la réponse

The reaction with the highest ΔH (change in enthalpy) would be the reaction between HCL and NaOH, which forms NaCL and H2O. This is because the formation of water releases energy in the form of heat, which is reflected in the positive ΔH value for this reaction. When an acid and a base react, they neutralize each other and form a salt and water, with the release of heat being a sign of an exothermic reaction.

Ethene, when passed into concentrated H2SO4, is rapidly absorbed. The product is diluted with water and then warmed to produce

Détails de la réponse

When ethene is passed into concentrated H2SO4, it undergoes electrophilic addition reaction to form ethyl hydrogen sulfate as the product. The reaction mixture is then diluted with water and warmed to produce ethanol as the main product. Therefore, the answer is ethanol.

 The function of sulphur during the vulcanization of rubber is to

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The function of sulphur during the vulcanization of rubber is to form chains which bind rubber molecules together.

An organic compound which decolorizes bromine water is likely to be?

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The oxidation number of oxygen in BaO2 is

Détails de la réponse

To determine the oxidation number of oxygen in BaO2, we can use the fact that the overall charge of a compound must be zero. Barium (Ba) is a Group 2 element and has an oxidation state of +2. The compound BaO2 has no net charge, so the sum of the oxidation states of all the atoms must be zero. Let x be the oxidation state of oxygen in BaO2. Therefore, we have: (+2) + 2(x) = 0 Solving for x, we get: x = -1 Therefore, the oxidation number of oxygen in BaO2 is -1.

Copper (II) tetraoxosulphate (IV) is widely used as

Détails de la réponse

Copper (II) tetraoxosulphate (IV), also known as copper sulfate or CuSO4, is widely used as a fungicide and a disinfectant. As a fungicide, copper sulfate is effective in controlling fungal diseases in plants, including mildew, leaf spots, and blights. It is also used as a fungicide in swimming pools to prevent the growth of algae. As a disinfectant, copper sulfate is effective in killing bacteria and viruses. It is used in a variety of applications, including in the production of animal feed, as a preservative for wood, and in water treatment to kill bacteria and algae. While copper sulfate has been used as a fertilizer in the past, its use in this capacity has largely been replaced by other compounds. It is not commonly used as a purifier.

 The boiling point of water, ethanol, toulene and butan-2-ol are 373.0k, 351.3k, 383.6k and 372.5k respectively, which liquid has the highest vapour pressure at 323.0k

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The sulphide that is commonly used in coating electric fluorescent tubes is?

Détails de la réponse

The sulphide commonly used in coating electric fluorescent tubes is Zinc Sulphide. Zinc Sulphide is a type of material that glows when it is exposed to ultraviolet light. When ultraviolet light is generated inside a fluorescent tube, it excites the Zinc Sulphide particles, causing them to emit visible light. This visible light is what we see as the bright light coming from the tube. So, Zinc Sulphide acts as a phosphor and helps in producing the bright light in fluorescent tubes.

Addition of sodium chloride to water to form a solution would  lead to?

Détails de la réponse

The addition of sodium chloride to water to form a solution would lead to a decrease in freezing point and an increase in boiling point. This effect is known as colligative properties, which depend on the concentration of solute particles in a solution. When sodium chloride dissolves in water, it breaks down into sodium ions and chloride ions. These ions occupy space between water molecules and interfere with the formation of ice crystals during freezing. As a result, the freezing point of the solution is lowered below that of pure water. This is why we use salt to de-ice roads and sidewalks during the winter season. Similarly, the presence of solute particles in a solution also raises the boiling point of the solution. The increased concentration of solute particles in the solution causes a decrease in the vapor pressure of the solvent (water), making it harder for the solvent molecules to escape into the gas phase. This means that more energy is required to bring the solution to its boiling point compared to pure water. In summary, the addition of sodium chloride to water forms a solution with lower freezing point and higher boiling point compared to pure water.

On the basis of the electrochemical series, which of these ions will show the greater tendency to be discharged at the cathode in an electrolytic cell

Détails de la réponse

The electrochemical series is a list of metals and ions arranged in order of their decreasing tendency to lose or gain electrons, and thus, their ability to act as reducing or oxidizing agents. The higher the position of a metal or ion in the electrochemical series, the greater its tendency to lose electrons and undergo oxidation, while the lower its position, the greater its tendency to gain electrons and undergo reduction. In an electrolytic cell, the cathode is the electrode where reduction occurs, meaning that cations (positively charged ions) are attracted and gain electrons to form neutral atoms or molecules. Based on the electrochemical series, the ion with the higher position in the series will have a greater tendency to gain electrons and be discharged at the cathode, while the ion with the lower position will have a lower tendency and may not be discharged at all. Among the given options, the electrochemical series order is: Cu2+ > Sn2+ > Fe2+ > Zn2+ Therefore, Cu2+ has the highest tendency to be discharged at the cathode and undergo reduction, while Zn2+ has the lowest tendency. So, in an electrolytic cell, Cu2+ will be discharged at the cathode, while Zn2+ may not be discharged at all, depending on the conditions of the cell.

6g of Mg was to 100cm3 of 1 moldm3 H2 SO4 . What mass of Mg remained undissolved? (Mg = 24)

Détails de la réponse

The balanced chemical equation for the reaction between magnesium (Mg) and sulfuric acid (H2SO4) is: Mg + H2SO4 -> MgSO4 + H2 According to the equation, one mole of Mg reacts with one mole of H2SO4 to produce one mole of magnesium sulfate (MgSO4) and one mole of hydrogen gas (H2). Since the concentration of the sulfuric acid is 1 moldm3, this means that there is one mole of H2SO4 in every 1 liter (1000 cm3) of solution. To determine the amount of Mg that reacts with the H2SO4, we need to use stoichiometry. One mole of Mg reacts with one mole of H2SO4, so the amount of Mg that reacts with 1 moldm3 of H2SO4 is given by: 6g / 24g/mol = 0.25 mol Since the reaction is 1:1, this means that 0.25 mol of H2SO4 is consumed in the reaction. The volume of the solution is 100cm3 (0.1 dm3), so the amount of H2SO4 in the solution is: 1 mol/dm3 x 0.1 dm3 = 0.1 mol The amount of H2SO4 that remains after the reaction is: 0.1 mol - 0.25 mol = -0.15 mol This negative value means that all of the H2SO4 was consumed in the reaction, and there is excess Mg left over. The mass of Mg that remains undissolved is given by: 0.15 mol x 24g/mol = 3.6g Therefore, the correct answer is 3.6g.

 The removal of rust from iron by treatment with tetraoxosulphate (vi) acid is based on the

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Which of the following roles does sodium chloride play in preparation? It

Détails de la réponse

The role that sodium chloride (NaCl) plays in soap preparation is to separate soap from glycerol. When fats or oils are hydrolyzed with an alkali, such as sodium hydroxide (NaOH), the result is a mixture of soap and glycerol. Adding NaCl to this mixture helps to induce the precipitation of the soap, allowing it to be separated from the glycerol. This process is known as "salting out" and is used to purify the soap and remove impurities. Sodium chloride does not react with glycerol or accelerate the decomposition of fat and oil. Also, it does not convert the fatty acid to its sodium salt as this conversion is done by the alkali (such as NaOH) during the saponification process.

Which of the following is stable to heat

Détails de la réponse

Out of the given options, K2CO3 is stable to heat.

An organic functional group which can likely decolorize ammoniacal silver nitrate is?

Détails de la réponse

The organic functional group that can likely decolorize ammoniacal silver nitrate is an alkyne. When ammoniacal silver nitrate is added to a solution containing an alkyne functional group, a white or yellowish precipitate of silver acetylide is formed. Silver acetylide is a highly explosive compound and is sparingly soluble in water, causing it to appear as a white or yellowish solid precipitate. This reaction is used as a test to detect the presence of an alkyne functional group in an organic compound. In contrast, alkanes, alkenes, and alkanols do not react with ammoniacal silver nitrate, so they cannot decolorize it. Therefore, an organic functional group that can likely decolorize ammoniacal silver nitrate is an alkyne.

The above table shows the compositions of the atmosphere of planet X. Which of these gases are present in higher percentages on earth?

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30 cm3 of oxygen at 10 atmosphere pressure is placed in a 20 dm3 container. Calculate the new pressure if the temperature is kept constant.

Détails de la réponse

Given:

• Initial pressure, 𝑃1=10P1​=10 atmospheres
• Initial volume, 𝑉1=30 cm3V1​=30cm3
• Final volume, 𝑉2=20 dm3V2​=20dm3

First, convert all volumes to the same units. Since 1 dm3dm3 is 1000 cm3cm3:

𝑉2=20 dm3=20×1000 cm3=20000 cm3V2​=20dm3=20×1000cm3=20000cm3

Now, using Boyle's Law:

𝑃1𝑉1=𝑃2𝑉2P1​V1​=P2​V2​

Substitute the known values into the equation:

10×30=𝑃2×2000010×30=P2​×20000

300=𝑃2×20000300=P2​×20000

Solve for 𝑃2P2​:

𝑃2=30020000P2​=20000300​

𝑃2=0.015 atmospheresP2​=0.015atmospheres

Therefore, the new pressure if the temperature is kept constant is:

An organic compound with fishy smell is likely to have a general formula?

Détails de la réponse

The organic compound with a fishy smell is most likely to have the general formula RNH2, which represents a primary amine. Amines are organic compounds that contain a nitrogen atom bonded to one or more carbon atoms. Primary amines have one alkyl or aryl group and two hydrogen atoms bonded to the nitrogen atom. Some primary amines have a fishy smell, which is caused by the presence of volatile amines. These amines are small molecules that can easily evaporate and have a strong odor, similar to that of fish. Examples of compounds that have a fishy smell include trimethylamine, which is found in fish, and butylamine, which is used in the production of rubber and pharmaceuticals. In summary, the organic compound with a fishy smell is likely to have the general formula RNH2, which represents a primary amine.

When marble is heated to 1473K, another whiter solid is obtained which reacts vigoriously with water to give an alkaline solution. The solution contains

Détails de la réponse

The white solid obtained when marble (calcium carbonate, CaCO3) is heated to 1473K is calcium oxide (CaO), also known as quicklime. When quicklime reacts vigorously with water, it forms calcium hydroxide (Ca(OH)2), which is an alkaline solution. Therefore, the solution obtained from the reaction of quicklime with water contains calcium hydroxide (Ca(OH)2).

Which of the following best represent solid gas mixture?

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In the extraction of iron, hot air is introduced into the blast furnace through?

Détails de la réponse

In the extraction of iron, hot air is introduced into the blast furnace through tuyeres. Tuyeres are nozzles that are located at the bottom of the blast furnace, and they are used to blow hot air into the furnace. The hot air helps to burn the coke (a fuel made from coal) which provides the heat needed to melt the iron ore. The air also helps to remove the waste gases that are produced during the reaction, allowing the iron to be extracted more efficiently.

Electrons enter into orbitals in order of increasing energy as exemplified by?

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An organic compound decolourized acidified KMnO4 solution but failed to react with ammonical AgNO3 solution. The organic compound is likely?

Détails de la réponse

The given information suggests that the organic compound is an unsaturated compound (because it decolorized the acidified KMnO4 solution), but it does not contain a functional group that reacts with ammonical AgNO3 solution. Therefore, the likely organic compound is an alkene or an alkyne. Carboxylic acids can also react with acidified KMnO4 solution, but they would also react with ammonical AgNO3 solution to form a silver carboxylate salt. Alkanes are saturated compounds and do not react with either reagent, so they would not decolorize the acidified KMnO4 solution. Therefore, based on the given information, the most likely option is either an alkene or an alkyne.