JAMB UTME - Chemistry - 2022

Détails de la réponse

The correct answer is: "melting does not break the metallic bond but boiling does." The metallic bond is the force of attraction between metal atoms, which holds them together to form a solid. When a metal is heated, its temperature increases, and at a certain point, the energy provided by the heat is enough to overcome the metallic bond and cause the metal to melt. However, even in the liquid state, the metallic bond remains intact, which is why metals have a very high melting point. On the other hand, when the temperature is further increased, the energy provided by the heat becomes enough to break the metallic bond, and the metal atoms become completely detached from one another. This results in the metal boiling and turning into a gas. Because the metallic bond is much stronger than other types of intermolecular forces, such as van der Waals forces, it requires a lot of energy to break, resulting in a large temperature interval between the melting point and boiling point of metal.

Détails de la réponse

The role that sodium chloride (NaCl) plays in soap preparation is to separate soap from glycerol. When fats or oils are hydrolyzed with an alkali, such as sodium hydroxide (NaOH), the result is a mixture of soap and glycerol. Adding NaCl to this mixture helps to induce the precipitation of the soap, allowing it to be separated from the glycerol. This process is known as "salting out" and is used to purify the soap and remove impurities. Sodium chloride does not react with glycerol or accelerate the decomposition of fat and oil. Also, it does not convert the fatty acid to its sodium salt as this conversion is done by the alkali (such as NaOH) during the saponification process.

Détails de la réponse

Détails de la réponse

Détails de la réponse

The balanced chemical equation for the reaction between magnesium (Mg) and sulfuric acid (H2SO4) is: Mg + H2SO4 -> MgSO4 + H2 According to the equation, one mole of Mg reacts with one mole of H2SO4 to produce one mole of magnesium sulfate (MgSO4) and one mole of hydrogen gas (H2). Since the concentration of the sulfuric acid is 1 moldm3, this means that there is one mole of H2SO4 in every 1 liter (1000 cm3) of solution. To determine the amount of Mg that reacts with the H2SO4, we need to use stoichiometry. One mole of Mg reacts with one mole of H2SO4, so the amount of Mg that reacts with 1 moldm3 of H2SO4 is given by: 6g / 24g/mol = 0.25 mol Since the reaction is 1:1, this means that 0.25 mol of H2SO4 is consumed in the reaction. The volume of the solution is 100cm3 (0.1 dm3), so the amount of H2SO4 in the solution is: 1 mol/dm3 x 0.1 dm3 = 0.1 mol The amount of H2SO4 that remains after the reaction is: 0.1 mol - 0.25 mol = -0.15 mol This negative value means that all of the H2SO4 was consumed in the reaction, and there is excess Mg left over. The mass of Mg that remains undissolved is given by: 0.15 mol x 24g/mol = 3.6g Therefore, the correct answer is 3.6g.

Détails de la réponse

The liquid is most likely to be option number 4: CH3OHCHOH2OH, which is also known as glycerol or glycerin. Glycerol has a high boiling point of 290°C, which is much higher than the boiling points of the other options. It is also a viscous liquid, which means it is thick and sticky. Glycerol is non-toxic, and it is often used in food, pharmaceuticals, and cosmetics. Furthermore, glycerol is miscible with water, which means that it can be easily mixed with water to form a homogeneous solution. It is also hygroscopic, which means that it can absorb water from the air. These properties make glycerol a useful substance in many applications, such as as a moisturizer in skincare products or as a humectant in food processing.

Détails de la réponse

The electrochemical series is a list of metals and ions arranged in order of their decreasing tendency to lose or gain electrons, and thus, their ability to act as reducing or oxidizing agents. The higher the position of a metal or ion in the electrochemical series, the greater its tendency to lose electrons and undergo oxidation, while the lower its position, the greater its tendency to gain electrons and undergo reduction. In an electrolytic cell, the cathode is the electrode where reduction occurs, meaning that cations (positively charged ions) are attracted and gain electrons to form neutral atoms or molecules. Based on the electrochemical series, the ion with the higher position in the series will have a greater tendency to gain electrons and be discharged at the cathode, while the ion with the lower position will have a lower tendency and may not be discharged at all. Among the given options, the electrochemical series order is: Cu2+ > Sn2+ > Fe2+ > Zn2+ Therefore, Cu2+ has the highest tendency to be discharged at the cathode and undergo reduction, while Zn2+ has the lowest tendency. So, in an electrolytic cell, Cu2+ will be discharged at the cathode, while Zn2+ may not be discharged at all, depending on the conditions of the cell.

Détails de la réponse

Détails de la réponse

According to Charles's Law, the ratio of the initial and final temperatures is equal to the ratio of the initial and final volumes at constant pressure. The ratio of the final volume to the initial volume is: Vf / Vi = 7.5 dm3 / 2.5 dm3 = 3 Therefore, the ratio of the final temperature to the initial temperature is also 3: Tf / Ti = Vf / Vi = 3 So the answer is 3:1.

Détails de la réponse

To determine the oxidation number of oxygen in BaO2, we can use the fact that the overall charge of a compound must be zero. Barium (Ba) is a Group 2 element and has an oxidation state of +2. The compound BaO2 has no net charge, so the sum of the oxidation states of all the atoms must be zero. Let x be the oxidation state of oxygen in BaO2. Therefore, we have: (+2) + 2(x) = 0 Solving for x, we get: x = -1 Therefore, the oxidation number of oxygen in BaO2 is -1.

Détails de la réponse

Détails de la réponse

The metal that can liberate hydrogen gas from steam is iron. The metal activity series is a list of metals in order of their reactivity, with the most reactive metals at the top and the least reactive metals at the bottom. When a metal is placed in a solution of steam (water vapor), the metal will react with the steam if it is more reactive than hydrogen. In this case, iron is more reactive than hydrogen, so it can displace hydrogen from the steam to form hydrogen gas. This reaction can be represented by the equation: Fe + H2O (steam) → FeO (iron oxide) + H2 (hydrogen gas) So, when steam is passed over iron, hydrogen gas is liberated and iron oxide is formed.

Détails de la réponse

The function of sulphur during the vulcanization of rubber is to form chains which bind rubber molecules together.

Détails de la réponse

Out of the given options, K2CO3 is stable to heat.

Détails de la réponse

Among the given options, only CuS will precipitate in dilute HCl. CuS is insoluble in dilute HCl, and hence it will precipitate when added to dilute HCl. However, the other options will dissolve in dilute HCl, and hence they will not precipitate. ZnS will dissolve in dilute HCl to form ZnCl2 and H2S. Na2S will react with dilute HCl to produce H2S and NaCl. FeS will dissolve in dilute HCl to form FeCl2 and H2S. Therefore, the correct answer is (4) CuS.

Détails de la réponse

An acidic oxide is an oxide that reacts with water to form an acidic solution. Non-metals have a greater tendency to form acidic oxides than metals. Therefore, among the given options, the non-metal that does not form an acidic oxide with oxygen would be the one that does not react with water to form an acidic solution. Out of the given options, chlorine is the non-metal that does not form acidic oxides with oxygen. Chlorine reacts with oxygen to form a number of oxides such as chlorine monoxide (Cl2O), chlorine dioxide (ClO2), and chlorine trioxide (ClO3), but none of these oxides react with water to form an acidic solution. Instead, they react with water to form oxyacids or oxoacids such as hypochlorous acid (HClO), chlorous acid (HClO2), and chloric acid (HClO3), which are stronger acids than the oxides. Therefore, the correct answer is chlorine.

Détails de la réponse

The most suitable catalyst for the given reaction is vanadium(V)oxide (V2O5). Vanadium(V)oxide is a commonly used catalyst for the oxidation of sulfur dioxide (SO2) to sulfur trioxide (SO3). The reaction is an exothermic reaction, and it occurs at high temperatures (around 450-500°C) in the presence of a catalyst. V2O5 is an effective catalyst for this reaction because it has a high surface area and can provide active sites for the reaction to occur. The vanadium ions in the V2O5 catalyst undergo redox reactions with the sulfur dioxide and oxygen molecules, which promotes the formation of sulfur trioxide. Chromium(VI)oxide and iron(III)oxide are not suitable catalysts for this reaction because they are not effective at promoting the oxidation of sulfur dioxide to sulfur trioxide. Copper(I)oxide can be used as a catalyst for the reaction, but it is not as effective as vanadium(V)oxide.

Détails de la réponse

The method employed in the preparation of salts will depend on the composition of the salt. Different salts have different chemical properties, and the method used to prepare them will depend on these properties. For example, some salts can be easily dissolved in water, while others are not very soluble and may require the use of a different solvent or special conditions to dissolve. The dissociating ability, stability to heat, and precipitating ability of the salt may also play a role in determining the preparation method, but the most important factor is the composition of the salt.

Détails de la réponse

Chlorine is not a common bleaching agent for wet litmus paper, wet pawpaw leaf, and most wet fabric dyes. It is commonly used as a bleaching agent for printer's ink.

Détails de la réponse

Détails de la réponse

The atomic number of an atom represents the number of protons in the nucleus of the atom. Since the atomic number given is 17, it means that there are 17 protons in the nucleus. The mass number of an atom represents the total number of protons and neutrons present in the nucleus. Therefore, if the mass number is given as 37, it means that the total number of protons and neutrons in the nucleus is 37. To determine the number of neutrons in the nucleus, we can subtract the atomic number (which represents the number of protons) from the mass number (which represents the total number of protons and neutrons). Thus, the number of neutrons in the atom with a mass number of 37 and an atomic number of 17 is: Number of neutrons = Mass number - Atomic number = 37 - 17 = 20 Therefore, the answer is 20.

Détails de la réponse

The reason why calcium forms complexes with ammonia is that it has empty d-orbitals.

Détails de la réponse

Détails de la réponse

Détails de la réponse

Hard water is water that contains high amounts of dissolved minerals, specifically calcium and magnesium ions. These minerals come from the rocks and soil that the water flows through and can accumulate in the water as it travels to your home. When you use hard water, it can leave mineral deposits on your pipes, fixtures, and appliances, which can reduce their efficiency and lifespan. It can also make soap less effective and leave your skin feeling dry and itchy. Therefore, it is important to treat hard water if it is a problem in your area.

Détails de la réponse

The sulphide commonly used in coating electric fluorescent tubes is Zinc Sulphide. Zinc Sulphide is a type of material that glows when it is exposed to ultraviolet light. When ultraviolet light is generated inside a fluorescent tube, it excites the Zinc Sulphide particles, causing them to emit visible light. This visible light is what we see as the bright light coming from the tube. So, Zinc Sulphide acts as a phosphor and helps in producing the bright light in fluorescent tubes.

Détails de la réponse

Détails de la réponse

Détails de la réponse

In the extraction of iron, hot air is introduced into the blast furnace through tuyeres. Tuyeres are nozzles that are located at the bottom of the blast furnace, and they are used to blow hot air into the furnace. The hot air helps to burn the coke (a fuel made from coal) which provides the heat needed to melt the iron ore. The air also helps to remove the waste gases that are produced during the reaction, allowing the iron to be extracted more efficiently.

Détails de la réponse

Détails de la réponse

Détails de la réponse

The active component of baking powder is sodium bicarbonate (NaHCO3). It is responsible for the leavening or rising of baked goods by releasing carbon dioxide gas when it reacts with an acid. Other ingredients in baking powder, such as monocalcium phosphate and sodium aluminum sulfate, provide the acid component for the reaction to occur. Magnesium sulfate (MgSO4) and calcium sulfate (CaSO4) are not typically used in baking powder, and sodium chloride (NaCl) is simply table salt and not an active ingredient in leavening.

Détails de la réponse

Détails de la réponse

Graphite is the option that conducts electricity.

Détails de la réponse

The reaction with the highest ΔH (change in enthalpy) would be the reaction between HCL and NaOH, which forms NaCL and H2O. This is because the formation of water releases energy in the form of heat, which is reflected in the positive ΔH value for this reaction. When an acid and a base react, they neutralize each other and form a salt and water, with the release of heat being a sign of an exothermic reaction.

Détails de la réponse

Carbon dioxide (CO2) has a linear molecular geometry, with two oxygen atoms bonded to the central carbon atom. Each bond between carbon and oxygen is a double bond, consisting of two pairs of electrons shared between the atoms. Therefore, there are two bonding pairs in each of the carbon-oxygen double bonds, giving a total of four bonding pairs in CO2. The answer is 4.

Détails de la réponse

Given:

• Initial pressure, 𝑃1=10P1​=10 atmospheres
• Initial volume, 𝑉1=30 cm3V1​=30cm3
• Final volume, 𝑉2=20 dm3V2​=20dm3

First, convert all volumes to the same units. Since 1 dm3dm3 is 1000 cm3cm3:

𝑉2=20 dm3=20×1000 cm3=20000 cm3V2​=20dm3=20×1000cm3=20000cm3

Now, using Boyle's Law:

𝑃1𝑉1=𝑃2𝑉2P1​V1​=P2​V2​

Substitute the known values into the equation:

10×30=𝑃2×2000010×30=P2​×20000

300=𝑃2×20000300=P2​×20000

Solve for 𝑃2P2​:

𝑃2=30020000P2​=20000300​

𝑃2=0.015 atmospheresP2​=0.015atmospheres

Therefore, the new pressure if the temperature is kept constant is:

Détails de la réponse

The oxidizing and reducing properties of a substance depend on its ability to gain or lose electrons. A substance that can gain electrons acts as an oxidizing agent, while a substance that can lose electrons acts as a reducing agent. Among the given options, both Cl2 (chlorine gas) and SO2 (sulfur dioxide) can act as both oxidizing and reducing agents depending on the reaction conditions. - Cl2 can act as an oxidizing agent when it gains electrons to form Cl- ions, and it can act as a reducing agent when it loses electrons to form Cl+ ions. For example, in the reaction Cl2 + 2KBr → 2KCl + Br2, chlorine gas is acting as an oxidizing agent since it is gaining electrons from bromide ions to form bromine gas. However, in the reaction 2Cl- + Cl2 → 2Cl2-, chlorine gas is acting as a reducing agent since it is losing electrons to form chloride ions. - SO2 can act as an oxidizing agent when it gains electrons to form sulfite ions (SO32-), and it can act as a reducing agent when it loses electrons to form sulfur trioxide (SO3). For example, in the reaction SO2 + 2H2S → 3S + 2H2O, sulfur dioxide is acting as a reducing agent since it is losing electrons to form elemental sulfur. However, in the reaction 2SO32- + O2 → 2SO42-, sulfur dioxide is acting as an oxidizing agent since it is gaining electrons to form sulfate ions. H2S (hydrogen sulfide) and NH3 (ammonia) are not likely to act as both oxidizing and reducing agents under normal conditions. H2S tends to act as a reducing agent by donating electrons to oxidizing agents, while NH3 tends to act as a reducing agent by donating electrons to oxidizing agents or as a base by accepting protons.

Détails de la réponse

The degree of disorder of the system increases as boiling water changes to steam. When water is boiled and changes to steam, the water molecules gain energy and become more disordered, which means that the molecules move more rapidly and the entropy of the system increases. The temperature of the system also increases during this process, but the degree of disorder is the factor that specifically increases as the water changes to steam. The number of molecules and activation energy remain constant during this phase transition.

Détails de la réponse

The pollutant that is usually present in a city that generates its electricity from coal is sulfur dioxide (SO2), also known as sulfur(iv)oxide. When coal is burned to generate electricity, sulfur compounds in the coal are released into the air as SO2. This gas can react with other pollutants and atmospheric conditions to form smog, which can be harmful to human health and the environment. Therefore, it is important to reduce the use of coal in electricity generation and promote cleaner and more sustainable energy sources to reduce the levels of SO2 and other harmful pollutants in the air.