The action of blotting paper on ink is due to capillarity.
Capillarity is the ability of a liquid to flow in narrow spaces, such as the fibers of a piece of blotting paper, against the force of gravity. This is made possible because of the combination of the liquid's surface tension, which acts like a skin on the surface of the liquid, and the wicking action of the fibers in the paper. The fibers in the blotting paper wick the ink from the surface it is on, and the ink is held in the fibers due to the surface tension of the liquid. This is why blotting paper is effective in removing excess ink from surfaces, because it pulls the ink into its fibers and holds it there.