Without considering the containing vessel, what mass of boiled water can raise the temperature of 8 kg of water from 25°C to 60°C when mixed in a heat-proof...

Answer Details

This is a method-of-mixtures problem, and the governing statement is the principle of conservation of energy: with the container ignored and no loss to the surroundings, \[\text{heat lost by the hot water} = \text{heat gained by the cold water}.\] Each term is calculated from \(Q = mc\,\Delta\theta\). Boiled water is at \(100\,^\circ\text{C}\), and the final mixture temperature is \(60\,^\circ\text{C}\), so the temperature changes are:

• hot water cools from \(100\,^\circ\text{C}\) to \(60\,^\circ\text{C}\): \(\Delta\theta = 40\,\text{K}\)
• cold water warms from \(25\,^\circ\text{C}\) to \(60\,^\circ\text{C}\): \(\Delta\theta = 35\,\text{K}\)

Both liquids are water, so the specific heat capacity \(c\) is the same on each side and cancels: \[m \times c \times 40 = 8 \times c \times 35\] \[40m = 280 \quad\Rightarrow\quad m = 7\,\text{kg}.\] Seven kilograms of boiled water is required.

Three points decide this question. First, "boiled water" fixes the hot temperature at \(100\,^\circ\text{C}\); it is data given in words rather than symbols. Second, the two temperature changes are different (\(40\,\text{K}\) against \(35\,\text{K}\)), so the masses cannot simply be equal, and the hot mass must be the smaller multiple: \(m/8 = 35/40\). Third, because both substances are water, \(c\) never needs a numerical value, so quoting \(4200\,\text{J kg}^{-1}\text{K}^{-1}\) adds arithmetic but no information. Also note that no latent heat appears here: nothing changes state, the steam having already condensed. In an examination, write out both \(\Delta\theta\) values explicitly before forming the equation, since reversing them is the commonest source of a wrong mass.