To evaluate the given expression, we need to perform matrix multiplication. We multiply the first row of the matrix on the left with the column matrix on the right as shown below:
\[\begin{pmatrix} 2 & 3 \\ 4 & 1 \end{pmatrix} \begin{pmatrix} 2 \\ 3 \end{pmatrix} = \begin{pmatrix} (2 \times 2) + (3 \times 3) \\ (4 \times 2) + (1 \times 3) \end{pmatrix} = \begin{pmatrix} 13 \\ 11 \end{pmatrix}\]
Therefore, the answer is \(\begin{pmatrix} 13 \\ 11 \end{pmatrix}\).