(b)i. Define the emf of a battery.
ii. A cell X of emf 1.018V is balanced by a length of 50.0cm on a potentiometer wire. Another cell Y is balanced by a length of 75.0cm on the same wire. Calculate the emf of Y.
Practical: current and jockey position on a potentiometer wire
With the standard resistor \(R\) and battery in circuit, the ammeter reading \(I\) is taken for each jockey contact position \(x\), and \(x^{-1}\) is evaluated. A specimen table (values illustrative):
| x (cm) | x\(^{-1}\) (cm\(^{-1}\)) | I\(_1\) (A) |
| 20 | 0.0500 | I\(_a\) |
| 35 | 0.0286 | I\(_b\) |
| 45 | 0.0222 | I\(_c\) |
| 60 | 0.0167 | I\(_d\) |
| 80 | 0.0125 | I\(_e\) |
Plot \(x^{-1}\) (vertical) against \(I_{1}\) (horizontal) from the origin; the graph is a straight line whose slope \(s = \dfrac{\Delta(x^{-1})}{\Delta I_{1}}\). Extrapolate to find \(l_{o}\), the value of \(I_{1}\) at \(x^{-1} = 0\), then evaluate \(\dfrac{I_{o}}{I}\).
Two precautions: ensure firm, clean jockey contacts and tap (do not drag) the jockey on the wire; check that all connections are tight and the key is opened between readings to avoid heating the wire and running down the cell.
(b)(i) EMF of a battery
The emf of a battery is the total electrical energy it supplies per unit charge driven round a complete circuit (the work done per coulomb by the battery), equal to the terminal p.d. when the battery delivers no current.
(b)(ii) EMF of cell Y
On a potentiometer the balance length is proportional to the emf, so \(\dfrac{E_{Y}}{E_{X}} = \dfrac{l_{Y}}{l_{X}}\).
\(E_{Y} = E_{X}\times\dfrac{l_{Y}}{l_{X}} = 1.018\times\dfrac{75.0}{50.0} = 1.018\times1.5 = 1.527\ \text{V}\).