TEST OF PRACTICAL KNOWLEDGE QUESTION All your burette readings (initial and final), as well as the size of your pipette, must be recorded but no account or ...
All your burette readings (initial and final), as well as the size of your pipette, must be recorded but no account or expeimental procedure is required. All calculations must be done in your answer book.
A is \(0.125\ \text{mol dm}^{-3}\) H\(_2\)SO\(_4\). B is a solution containing X \(\text{g dm}^{-3}\) of NaOH.
(a) Put A into the burette and titrate it against \(20.0\ \text{cm}^3\) or \(25.0\ \text{cm}^3\) portions of B using methyl orange as indicator. Record the volume of your pipette. Tabulate your burette readings and calculate the average volume of A used. The equation for the reaction involved in the titration is H\(_2\)SO\(_4\) + 2NaOH\(_{(aq)}\) \(\to\) Na\(_2\)SO\(_4\) + 2H\(_2\)O\(_{(l)}\)
(b) From your results and the information provided above, calculate the;
(i) amount of H\(_2\)SO\(_4\) in the average volume of A used
(ii) Concentration of B in \(\text{mol dm}^{-3}\)
(iii) value of X.
[H = 1: O = 16; Na = 23]
(c) Describe briefly a suitable laboratory procedure for obtaining pure water from the titration mixture. (No diagram is required)
(a) Titration results (pipette volume = 25.0 cm3 of B; indicator methyl orange, endpoint yellow to orange)
Rough
1st
2nd
3rd
Final reading (cm3)
24.00
23.25
23.15
23.20
Initial reading (cm3)
0.00
0.00
0.00
0.00
Volume of A used (cm3)
24.00
23.25
23.15
23.20
Average volume of A = (23.25 + 23.15 + 23.20) / 3 = 69.60 / 3 = 23.20 cm3.
X = concentration × molar mass = 0.232 × 40 = 9.28 g dm-3.
(c) Obtaining pure water from the titration mixture
The neutralised mixture is a solution of sodium tetraoxosulphate(VI) in water. Set it up for simple distillation: heat the mixture so that the water boils off, passes into the condenser and is collected as pure distillate, while the non-volatile sodium sulphate remains behind in the flask.
X = concentration × molar mass = 0.232 × 40 = 9.28 g dm-3.
(c) Obtaining pure water from the titration mixture
The neutralised mixture is a solution of sodium tetraoxosulphate(VI) in water. Set it up for simple distillation: heat the mixture so that the water boils off, passes into the condenser and is collected as pure distillate, while the non-volatile sodium sulphate remains behind in the flask.