WAEC SSCE - Chemistry - 1993

In which of the following changes is ∆S negative ?

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The change in entropy (∆S) is a measure of the disorder or randomness of a system. A negative ∆S indicates that there is a decrease in disorder or randomness. In the given options: - The first option is a phase change from liquid to solid, which is typically associated with a decrease in entropy. So, ∆S is negative. - The second option involves the formation of a gas, which is typically associated with an increase in entropy. So, ∆S is positive. - The third option involves the decomposition of a solid into gases, which is typically associated with an increase in entropy. So, ∆S is positive. - The fourth option is the dissociation of a salt into its ions, which is typically associated with an increase in entropy. So, ∆S is positive. - The fifth option involves the formation of a gas, which is typically associated with an increase in entropy. So, ∆S is positive. Therefore, the only change in which ∆S is negative is H₂O_(l) → H₂O_(s).

Starch undergoes complete hydrolysis to produce

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Starch is a polysaccharide, which is a type of carbohydrate made up of many glucose units linked together. Complete hydrolysis of starch breaks down these glucose units into their monomers, resulting in the production of glucose. Therefore, the correct answer is glucose.

Which of the following pairs illustrates isotopy?

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The pair that illustrates isotopy is hydrogen and deuterium. Isotopy refers to the phenomenon where two atoms of different elements have the same atomic number but different atomic masses due to a different number of neutrons in their nuclei. Hydrogen and deuterium are both elements with atomic number 1, but deuterium has one neutron in its nucleus in addition to the proton, while hydrogen has no neutron. Therefore, they are isotopes of each other. In contrast, the other options are not examples of isotopy. But-l-ene and but-2-ene are structural isomers, ortho-hydrogen and para-hydrogen are different spin isomers, oxygen and ozone are allotropes of the same element, and alpha and beta particles are different types of subatomic particles.

Consider the reaction represented by the following equation CaCI_{2 (aq)} + H ₂C₂O _4(aq) ⇌ CaC ₂O_4(s) + 2HCI_(aq). Which of the following would dissolve the precipitate of CaC ₂O₄ formed?

Maelezo ya Majibu

The formation of a precipitate in this reaction indicates that CaC ₂O₄ is insoluble in water. In order to dissolve the precipitate, we need to find a substance that can react with it to form a soluble compound. , adding concentrated hydrochloric acid, is the correct answer. This is because the reaction between CaC ₂O₄ and HCl produces soluble calcium chloride (CaCl ₂) and carbon dioxide (CO ₂). The balanced chemical equation for this reaction is: CaC ₂O₄ + 4HCl → CaCl ₂ + 2CO ₂ + 2H ₂O The carbon dioxide gas will escape as bubbles, leaving behind a solution of CaCl ₂, which is soluble in water. The other options will not dissolve the CaC ₂O₄ precipitate. Stirring the mixture vigorously will not change the chemical nature of the substances in the solution. Adding more calcium chloride solution will not react with the CaC ₂O₄ precipitate since it is already present in excess. Increasing the concentration of ethanedioic acid will not react with CaC ₂O₄ either, as it is a weak acid and cannot displace the strong acid HCl. Adding distilled water will not dissolve the precipitate since CaC ₂O₄ is insoluble in water.

What does X atand for in the following expression? X = Log₍₁₀₎(H⁺)

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In the expression X = Log₍₁₀₎(H⁺), the variable X stands for the degree of acidity, commonly known as pH. The pH of a solution is a measure of its hydrogen ion concentration. The logarithmic function in this expression relates the hydrogen ion concentration to the pH scale, which ranges from 0 to 14. A pH of 7 is considered neutral, while values below 7 are acidic and values above 7 are basic. The pH scale is widely used in chemistry and biology to describe the acidity or basicity of a solution, and it is an important parameter in many chemical reactions and biological processes.

Which of the following pieces of deposited if a current of 10A was passed through a solution of copper(ll) salt for 965 seconds? (1F = 96500 C)

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Which of the following compounds of tin is a strong reducing agent?

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The compound SnH₄ (tin(IV) hydride) is a strong reducing agent. This is because it can easily donate its hydrogen atoms, which act as reducing agents. In other words, SnH₄ can easily give up electrons to other compounds, causing them to be reduced. This property of SnH₄ makes it useful in a variety of chemical reactions, particularly in organic chemistry. On the other hand, SnCl₂, SnCl₄, SnO₂, and Sn(OH)₂ are not strong reducing agents. SnCl₂ and SnCl₄ are both tin(IV) compounds and do not contain any hydrogen atoms that can act as reducing agents. SnO₂ and Sn(OH)₂ contain oxygen and hydroxide groups respectively, which do not have a tendency to give up electrons and are not strong reducing agents.

Examples of polymers include the following except

Maelezo ya Majibu

Polymers are large molecules made up of repeating subunits called monomers. They can be natural or synthetic. Starch, nylon, wool, and perspex are examples of polymers because they are made up of repeating units of monomers. However, glass is not a polymer because it is not made up of repeating units of monomers. Instead, it is an amorphous solid that is made up of silicon dioxide (SiO2) molecules that are linked together in a random arrangement. Therefore, the correct answer is glass.

When ammonium chloride is dissolved in water in a test tube, the tube feels colder showing that

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The process is endothermic when ammonium chloride is dissolved in water in a test tube. When ammonium chloride is dissolved in water, it absorbs heat from the surroundings to break apart the ionic bonds between the ammonium and chloride ions. This means that the process requires energy to take place and absorbs heat from the surrounding environment. As a result, the test tube containing the solution feels colder to the touch, indicating that heat is being transferred from the surroundings to the solution. In summary, the cooling effect observed when ammonium chloride is dissolved in water in a test tube is due to the endothermic process of breaking apart ionic bonds, which absorbs heat from the surroundings.

An alkene may be converted to an alkane by

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An alkene is a hydrocarbon that contains a carbon-carbon double bond, whereas an alkane is a hydrocarbon that contains only single bonds between the carbon atoms. The process that converts an alkene to an alkane is called hydrogenation, which involves the addition of hydrogen gas (H2) across the carbon-carbon double bond. In this reaction, the double bond is broken, and the two carbon atoms are each bonded to a hydrogen atom, forming a single bond. This reaction is commonly carried out in the presence of a metal catalyst, such as platinum, palladium, or nickel, which speeds up the reaction by facilitating the adsorption of hydrogen molecules onto the surface of the metal. Therefore, the correct answer is hydrogenation.

Which of the following substances is a peroxide?

Maelezo ya Majibu

The substance that is a peroxide is Na2O2. A peroxide is a compound that contains an oxygen-oxygen single bond, also known as a peroxide linkage. Na2O2 is a peroxide because it contains the peroxide linkage between the two oxygen atoms in the formula. In contrast, CuO, Pb3O4, Fe2O3, and AI2O3 do not contain a peroxide linkage and are not peroxides. In summary, Na2O2 is the only substance in the given options that is a peroxide because it contains an oxygen-oxygen single bond, which is a defining characteristic of peroxides.

Which of the following gases are diatomic except

Maelezo ya Majibu

A diatomic molecule is a molecule composed of two atoms, whether they are of the same element or not. Therefore, the gases that are diatomic have molecules that consist of two atoms. Nitrogen, hydrogen, fluorine, and oxygen are diatomic gases, which means they exist as molecules composed of two atoms of the same element. On the other hand, helium is a monatomic gas, meaning it exists as individual atoms and not as molecules consisting of multiple atoms. Therefore, helium is the gas among the options given that is not diatomic.

When the trioxonitrate (IV) salt of an alkali metal Y is heated, the formula of the residue is

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In which of the following pairs are both substances deliquescent?

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Copper metal will react with concentrated trioxonitrate (V) acid to give?

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Which of the following is correct about the electrons in the 1s orbital? They

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The correct option about the electrons in the 1s orbital is that they are closest to the nucleus. The 1s orbital is the lowest energy level in an atom, and it is located closest to the nucleus, which has a positive charge. The closer an electron is to the nucleus, the stronger the attractive force between them, so electrons in the 1s orbital are more strongly attracted to the nucleus than those in other orbitals. This makes them harder to remove from the atom, and they require more energy to be ionized. The other options are not correct: electrons in the 1s orbital do not necessarily have the same spin, they are not easier to remove than those in the 2p orbital, they do not have the same energy as those in the 2s orbital, and they do not have different magnetic quantum numbers.

Some precious stones such as ruby and sapphire consist of aluminum oxide coloured by traces of the oxides of

Maelezo ya Majibu

Precious stones such as ruby and sapphire consist of aluminum oxide (Al₂O₃) colored by traces of transition metal oxides. The transition metal ions, such as chromium (Cr) and iron (Fe), replace some of the aluminum ions in the crystal lattice of the aluminum oxide, and give the stones their characteristic colors. For example, chromium gives rubies their red color and iron gives sapphires their blue color. Therefore, the correct option is "transition metals".

Chlorine is is used in water treatment as

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Chlorine is used in water treatment as a germicide. Water treatment is a process of purifying water to make it safe for human consumption. One of the most common methods of water treatment involves the use of chlorine. Chlorine is added to water to kill harmful microorganisms such as bacteria and viruses that can cause waterborne diseases like cholera, typhoid fever, and dysentery. Chlorine works by disrupting the cellular function of microorganisms and breaking down their cell walls. This makes them unable to reproduce and eventually causes them to die off. Chlorine is effective against a wide range of microorganisms and is relatively inexpensive compared to other water treatment methods. In summary, chlorine is used in water treatment as a germicide because it is effective at killing harmful microorganisms in water and making it safe for human consumption.

The product of the reaction between ethanol and excess acidified K_{2Cr2O2 is}

Maelezo ya Majibu

The product of the reaction between ethanol and excess acidified K_{2Cr2O2 is ethanoic acid. The reaction is an oxidation reaction where ethanol is oxidized to ethanoic acid and K2Cr2O2 is reduced to Cr³⁺. The acidified K2Cr2O2 acts as an oxidizing agent and removes hydrogen from the ethanol molecule, producing ethanoic acid. Therefore, the correct answer is ethanoic acid.}

The alloy used for metal work and plumbing contains

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Zinc displaces copper from an aqueous solution of copper (ll) salt because

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Zinc displaces copper from an aqueous solution of copper (II) salt because zinc is more reactive than copper. Reactivity is the tendency of a metal to lose electrons and form positive ions. Metals that have a higher tendency to lose electrons are more reactive than those with a lower tendency. Zinc is more reactive than copper, which means it has a greater tendency to lose electrons and form positive ions. When zinc is added to an aqueous solution of copper (II) salt, such as copper (II) sulfate, the zinc atoms lose electrons to form zinc ions. These zinc ions then react with the copper ions in the solution by displacing them from the copper (II) sulfate. The displaced copper ions then form a solid layer of copper on the surface of the zinc metal, which can be observed as a red-brown coating on the zinc. Therefore, the reason why zinc displaces copper from an aqueous solution of copper (II) salt is that zinc is more reactive than copper, and it has a greater tendency to lose electrons and form positive ions.

Producer gas is a mixture of

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Producer gas is a mixture of nitrogen and carbon (II) oxide. Producer gas is a fuel gas that is produced by heating a carbon-based fuel with a limited amount of oxygen or air. This process, called gasification, produces a mixture of gases that are collectively known as producer gas. The primary components of producer gas are nitrogen, which makes up the majority of the gas, and carbon (II) oxide, which is the second most abundant component. Other minor components may include hydrogen, methane, and other gases, depending on the type of fuel and the gasification process used. So, in summary, producer gas is mainly made up of nitrogen and carbon (II) oxide, with some minor amounts of other gases.

The component of air that removed when air is bubbled into alkaline pyrogallol solution is

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The component of air that is removed when air is bubbled into alkaline pyrogallol solution is oxygen. Alkaline pyrogallol solution is a reagent that is used to absorb oxygen from a gas mixture. When air is bubbled into this solution, the oxygen present in the air reacts with pyrogallol and gets absorbed, forming a brown precipitate of the oxidized pyrogallol. The other components of air, such as nitrogen, carbon dioxide, water vapor, and other gases, remain unchanged and do not react with pyrogallol. Therefore, the correct answer is: - Oxygen

Which of the following will not affect the degree of hardness in a sample of temporarily hard water?

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What volume of distilled water should be added to 400cm3 of 2.0 mole dm-3 \(H_{2}SO_{4}\) to obtain 0.20 mole dm-3 of solution>

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This is a dilution problem in chemistry. The formula for dilution is C₁V₁ = C₂V₂, where C₁ and V₁ are the initial concentration and volume, respectively, and C₂ and V₂ are the final concentration and volume, respectively. We can rearrange the formula to solve for V₂: V₂ = (C₁V₁)/C₂ Substituting the values given in the question, we get: V₂ = (2.0 mol dm^-3 x 400 cm³)/0.20 mol dm^-3 Simplifying the expression, we get: V₂ = 4,000 cm³ Therefore, 4,000cm³ of solution is needed. However, the question is asking for the volume of distilled water to add, so we need to subtract the initial volume from the final volume to get the volume of distilled water needed: Volume of distilled water = V₂ - V₁ = 4,000 cm³ - 400 cm³ = 3,600 cm³ Hence, the correct option is 3,600 cm³.

The following gases decolorize bromine water except

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Bromine water is a reddish-brown solution of bromine in water. When an unsaturated hydrocarbon gas (C₂H₄, C₂H₂, C₃H₄, C₃H₆) is passed through the bromine water, the double or triple bond of the hydrocarbon is broken, and the bromine is added across the double or triple bond. This results in the decolorization of the bromine water. On the other hand, when a saturated hydrocarbon gas such as ethane (C₂H₆) is passed through bromine water, there is no double or triple bond to break, and therefore no bromine is added to the molecule. Thus, bromine water is not decolorized by ethane. Therefore, the correct answer to the question is C₂H₆.

Which of the following indicates the correct increasing order of oxidizing power of the halogens?

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The oxidizing power of a halogen is related to its ability to gain electrons. Halogens have seven electrons in their outermost shell and require one more electron to complete their octet configuration. The process of gaining an electron involves reduction of the halogen. The halogens are arranged in the periodic table in order of increasing atomic number, so the trend in oxidizing power can be related to this arrangement. As we move down the group, the atomic radius of the halogens increases, and the valence electrons become farther away from the nucleus, which means it becomes harder to attract electrons and so the oxidizing power decreases. Therefore, the correct increasing order of oxidizing power of the halogens is: I < Br < Cl < F. Hence, is correct.

Which of the following separation is routinely applied in the petroleum industry

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The separation technique routinely applied in the petroleum industry is fractional distillation. Fractional distillation is a separation technique that separates a mixture of liquids into its individual components based on their boiling points. In the petroleum industry, crude oil, which is a mixture of various hydrocarbons, is heated and passed through a column that has several trays. Each tray has a different temperature, with the temperature increasing from the bottom to the top of the column. The hydrocarbons with lower boiling points vaporize and rise up the column, while those with higher boiling points remain as liquids and collect at the bottom. The vaporized hydrocarbons are then condensed and collected as fractions at different levels of the column. This process allows for the separation of crude oil into its individual components, such as gasoline, diesel, and kerosene.

Sulphur burns in air to form

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Sulphur burns in air to form an acidic oxide, which is sulfur dioxide (SO2). When sulfur burns in air, it reacts with oxygen to form sulfur dioxide gas. Sulfur dioxide is an acidic oxide because it reacts with water in the air to form sulfurous acid, which has a pH lower than 7. This means that it can react with bases to form salts and water. Sulfur dioxide is also a major air pollutant that can cause respiratory problems and acid rain when it dissolves in rainwater. In summary, when sulfur burns in air, it forms sulfur dioxide, which is an acidic oxide that can react with water to form sulfurous acid and can contribute to air pollution and acid rain.

Trioxosulphate (lV) acid is not stored for a long period because it

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Trioxosulphate (lV) acid, also known as sulfuric acid, is not stored for a long period because it is an unstable and easily decomposed compound. This means that over time, it breaks down into other substances, making it less effective for its intended use. Additionally, the decomposition of sulfuric acid can lead to the formation of hazardous byproducts, which can be dangerous if not properly handled. Therefore, it is essential to use and store sulfuric acid with caution and care.

Alkanes are used mainly

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Alkanes are primarily used as domestic and industrial fuels. Alkanes are a group of hydrocarbons that contain only single bonds between carbon atoms and are therefore relatively inert. They are obtained from crude oil and natural gas and can be used as fuels for heating and cooking in households and industries. In addition to their use as fuels, alkanes are also used in the production of plastics, where they serve as starting materials for the synthesis of various types of plastics. They are also used in the hydrogenation of oils to produce margarine, and as fine chemicals, where they are used as solvents, lubricants, and as a starting material in the synthesis of pharmaceuticals and other specialty chemicals. However, these applications are not as significant as their use as fuels.

Which of the following solids has a network structure?

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Diamond has a network structure. In a network structure, all the atoms in the solid are covalently bonded to each other forming a giant molecule. In diamond, each carbon atom is covalently bonded to four other carbon atoms forming a tetrahedral structure, creating a three-dimensional network of carbon atoms bonded together. This network structure is responsible for diamond's unique physical and chemical properties such as high hardness and thermal conductivity.

Carbon is often deposited in the exhaust-pipe of cars because of the

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The carbon deposits in the exhaust pipe of cars are caused by the incomplete combustion of petrol. When petrol is burned, it reacts with oxygen to produce carbon dioxide and water vapor. However, if there is not enough oxygen, the petrol can only partially burn, leading to the formation of carbon particles (soot) that get carried through the exhaust system and eventually settle in the exhaust pipe. The presence of additives in petrol or contamination with diesel would not directly cause carbon deposits in the exhaust pipe.

(a)(i) What is meant by the rate of a chemical reaction?

(ii) Explain in terms of the vision theory, the effect of temperature increase on reaction rate.

(b) When hydrogen peroxide is exposed to air, it decomposes

(i) Write an equation for the reaction.

(ii) Outline an experiment to illustrate that effect of a named catalyst on the rate of decomposition.

(iii) Sketch an energy profile diagram to show the effect of the catalyst on the reaction rate, given that the reaction is exothermic.

(c)(i) Explain why enthalpy data alone cannot be used to predict whether a reaction can occur spontaneously or not.

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None

(a)(i) Define the term polymerization.

(ii) List the three conditions required for the polymerization on of ethene.

(iii) State the property which is common to compounds that can be easily polymerized

(b) Write appropriate equations to show how the following can be obtained from propan-1-ol in the labouratory

(i) propene;

(ii) propylmethanoate. State the type of reaction involved in each case.

(c)(i) A compound contains 40.0% carbon, 6.7% hydrogen and 53.3% oxygen. Determine its molecular formula if its molar mass is 180 (H = 1, C = 12, O = 16)

(ii) Explain why ethanoic acid boils at a much higher temperature than butane even though their molar masses almost equal.

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None

(a) Name the residue obtained on strongly heating the following:

(i) ZnCO\(_3\) in an open crucible;

(ii) CuSO\(_4\), 5H\(_2\)O and then allowing it to cool in a desiccator.

(b) State the colour changes observed on heating and cooling in each case in(a) above.

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None

 Mention the respective properties of the following allotropes of carbon that account for their uses as indicated:

(a) diamond used for drilling rocks;

(b) diamond used as jewels;

(c) graphite used as electrodes;

(d) graphite used for slowing down neutrons in nuclear reactors;

(e) wood charcoal used in gas masks.

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None

(a) State the phenomenon illustrated by the:

(i) spreading of the smell of hydrogen sulphide gas in the laboratory;

(ii) existence of atoms of the same element having different mass numbers

(b) The atomic number of an element is 17. It has different atoms containing 18 neutrons and 20 neutrons, with a relative abundance of 75% and 25% respectively. Calculate the relative atomic mass of the element.

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None

Classify each of the following as physical change or a chemical change:

(a) fractional distillation of liquefied air;

(b) cracking of petroleum fractions;

(c) conversion of rhombic sulphur to monoclinic sulphur;

(d) chromatographic separation of chlorophyll.

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None

(a) If L is the Avogadro constant and E° is standard cell potential, state what X and Y stand for in the following expressions

(i) X = \(\frac{\text{Mass of L molecules of gas or vapour}}{\text{ Mass of L molecules of hydrogen}}\)

(ii) Y = -nFE°

(b) State two differences between a primary cell and a secondary cell.

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None

The compound whose formula is written below is a major component of a soft fatty substance:

(a) State the change that would be observed in the physical state of the fatty substance if hydrogen were bubbled through it for long time in the presence of finely divided nickel at about 180\(^o\)C

(c) Determine the amount (in mole) of hydrogen that would be consumed if one mole of the component reacted completely with hydrogen.

(c) State the product of the reaction of the fatty substance with hot concentrated sodium hydroxide solution

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None

(a)(i) List four characteristic properties of transition metals

(ii) Name two metals that can be extracted from their ore by electrolysis.

(b)(i) Determine the oxidation number of chromium in Cr\(_2\)O\(^{2-}_{7}\)

(ii) State the colour observed on adding a few drops of dilute tetraoxosulphate (VI) acid to the system representedby the following equation: Cr\(_2\)O\(^{2-}_{7(aq)}\) + H\(_2O_{(l)}\) \(\rightleftharpoons\) 2CrO\(^{2-}_{4(aq)}\) + 2H\(^+_{(aq)}\). Explain your answer.

(c)(i) State and explain what would be observed if hydrogen sulphide gas were bubbled into acidified K\(_2\)Cr\(_2\)O\(_7\). Write an equation for the reaction.

(ii) What precaution should be taken to avoid excessive exposure to hydrogen sulphide gas while it is being generated in the laboratory?

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None

(a) X and Y belong to the same period in the Periodic Table is a group I element while Y belongs to group VII. State which of the elements would

(i) be a good oxidizing agent

(ii) have the smaller atomic volume

(iii)  have the higher ionization potential

(b) Explain your answer in (a)(i) above.

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None

(a) State one air pollution that causes:

(i) blood poisoning

(ii) acid poisoning

(iii) blackening of the walls of buildings

(b) Mention one major chemical industry in each case which requires the following as raw materials:

(i) petrochemicals;

(ii) cellulose.

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None

(a)(i) Distinguish between a strong acid and a concentrated acid.

(ii) What is meant by amphoteric oxide? Give one example.

(b)(i) Describe the manufacture of tetraoxosulphate (VI) acid by contact process.

(ii) Write one equation each to show the action of tetraoxosulphate (VI) acid respectively as a dehydrating agent and as an oxidizing agent.

(iii) Give the reason why tetraoxosulphate classified as a heavy chemical.

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None

State which of the following can exhibit geometric isomerism:

Give reason for your answer

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None

(a) Give one disadvantage of:

(i) hard water

(ii) soft water

(b) Explain why the degree of hardness in a sample of clear lime water is higher than in another sample has that been turned milky by carbon (IV) oxide.

Maelezo ya Majibu

None